CMP compositions and methods for selective removal of silicon nitride
The present invention provides chemical mechanical polishing compositions and methods for polishing a substrate comprising silicon dioxide and silicon nitride, which provide selective removal of SiN relative to silicon oxide (e.g., PETEOS) on patterned wafers. In one embodiment, a CMP method comprises abrading a surface of a substrate comprising SiN and silicon oxide with a CMP composition to remove at least some SiN therefrom. The CMP composition comprises, consists essentially of, or consists of a particulate abrasive (e.g., ceria) suspended in an aqueous carrier and containing a cationic polymer bearing pendant quaternized nitrogen-heteroaromatic moieties, wherein the composition has a pH of greater than about 3.
1. A chemical mechanical polishing (CMP) method for selectively removing silicon nitride relative to silicon oxide from a substrate comprising silicon nitride and silicon oxide, the method comprising abrading a surface of the substrate with a CMP composition to remove at least some silicon nitride therefrom; the CMP composition comprising a particulate abrasive suspended in an aqueous carrier containing a cationic polymer bearing pendant quaternized nitrogen-heteroaryl moieties; wherein the composition has a pH of about 7.1 to about 9.5 and the cationic polymer is present at a concentration sufficient for at least a portion of the polymer to adsorb on the surface of the abrasive particles to maintain a zeta potential of at least +20 mV on the surface of the particles of the particulate abrasive at a basic pH.
2. The method of claim 1 wherein the particulate abrasive comprises colloidal ceria.
3. The method of claim 1 wherein the particulate abrasive has a mean particle size of about 10 to about 200 nm.
4. The method of claim 1 wherein the abrasive is present in the CMP composition at a concentration of about 0.1 to about 0.5 percent by weight (wt %), and the cationic polymer is present in the CMP composition at a concentration of about 20 to about 100 parts-per-million (ppm).
5. The method of claim 1 wherein the cationic polymer comprises a plurality of repeating units of formula —CH2CHR— in which R is a quaternized nitrogen heteroaryl moiety.
6. The method of claim 1 wherein the cationic polymer is selected from the group consisting of a quaternized poly(vinylpyridine), a quaternized poly(vinylimidazole) and a combination thereof.
7. The method of claim 1 wherein the cationic polymer comprises a poly(vinyl-N-methylpyridinium) homopolymer, a poly(N1-vinyl-N3-methylimidazolium) homopolymer, or a combination thereof.
8. The method of claim 1 wherein the cationic polymer includes one or more counter-ions selected from the group consisting of a halide, nitrate, and methylsulfate.
9. The method of claim 1 wherein the abrading is accomplished in conjunction with a polishing pad in a CMP polishing apparatus.
10. A chemical mechanical polishing (CMP) composition suitable for selectively removing silicon nitride relative to silicon oxide from a substrate comprising silicon nitride and silicon oxide; the composition containing a cationic polymer bearing pendant quaternized nitrogen-heteroaryl moieties; wherein the composition has a pH of about 7.1 to about 9.5 and the cationic polymer is present at a concentration sufficient for at least a portion of the polymer to adsorb on the surface of the abrasive particles to maintain a zeta potential of at least +20 mV on the surface of the particles of the particulate abrasive at a basic pH.
11. The CMP composition of claim 10 wherein the particulate abrasive comprises colloidal ceria.
12. The CMP composition of claim 10 wherein the particulate abrasive has a mean particle size of about 10 to about 200 nm.
13. The CMP composition of claim 10 wherein the particulate abrasive is present in the composition at a concentration of about 0.1 to about 2 wt %.
14. The CMP composition of claim 10 wherein the cationic polymer is present in the composition at a concentration of about 20 to about 500 ppm.
15. The CMP composition of claim 10 wherein the cationic polymer comprises a plurality of repeating units of formula —CH2CHR— in which R is a quaternized nitrogen heteroaryl moiety.
16. The CMP composition of claim 10 wherein the cationic polymer is selected from the group consisting of a quaternized poly(vinylpyridine), a quaternized poly(vinylimidazole) and a combination thereof.
17. The CMP composition of claim 10 wherein the cationic polymer comprises a poly(vinyl-N-methylpyridinium) homopolymer, a poly(N1-vinyl-N3-methylimidazolium) homopolymer, or a combination thereof.
18. The CMP composition of claim 10 wherein the cationic polymer includes one or more counter-ions selected from the group consisting of a halide, nitrate, and methylsulfate.