CMP polishing pad having edge exclusion region of offset concentric groove pattern

1. A polishing pad, wherein the polishing pad is characterized by a generally circular cross section, wherein the polishing pad comprises an axis of rotation and a polishing surface, wherein the polishing surface comprises at least a grooved region and an exclusion region, wherein the grooved region comprises a plurality of grooves set into the polishing surface, wherein the plurality of grooves is composed of at least a first plurality of concentric grooves having a first center of concentricity, wherein the axis of rotation of the polishing pad is not coincident with the first center of concentricity, wherein the plurality of grooves is further composed of a second plurality of concentric grooves having a second center of concentricity, wherein the first center of concentricity is not coincident with the second center of concentricity, and wherein the axis of rotation of the polishing pad is not coincident with the first center of concentricity and the second center of concentricity, wherein the exclusion region is devoid of grooves, wherein the exclusion region is adjacent to the circumference of the polishing pad, wherein the exclusion region has an outer boundary and an inner boundary, wherein the outer boundary of the exclusion region is contiguous with the circumference of the polishing pad, and wherein a distance from the circumference of the polishing pad to the inner boundary of the exclusion region is greater than zero.

2. The polishing pad of claim 1 , wherein an average distance from the circumference of the polishing pad to the inner boundary of the exclusion region is denoted by D A , and wherein D A is about 0.1 cm to about 2 cm.

3. The polishing pad of claim 2 , wherein D A is about 1 cm to about 1.5 cm.

4. The polishing pad of claim 3 , wherein D A has a standard deviation of about 0.5 or less.

5. A method of chemical-mechanically polishing a substrate, which method comprises:

(a) contacting a substrate with a chemical-mechanical polishing composition and the polishing pad of claim 1 ,

(b) moving the polishing pad relative to the substrate with the chemical-mechanical polishing composition therebetween, and

(c) abrading at least a portion of the substrate to polish the substrate.

6. The method of claim 5 , wherein a defect count on a surface of the substrate is lower than the defect count on the surface of the substrate when using an otherwise identical polishing pad that does not contain the exclusion region under identical polishing conditions.

7. The method of claim 5 , wherein the substrate comprises copper, and wherein at least some of the copper is removed from the substrate to polish the substrate.