Polishing composition comprising an amine-containing surfactant
View Patent ↗The invention provides a chemical-mechanical polishing composition comprising (a) wet-process ceria abrasive, (b) a surfactant comprising an amine-containing anchor group and ethylene oxide-propylene oxide stabilizing group, wherein the surfactant has a molecular weight of from about 1000 Daltons to about 5000 Daltons, (c) an aromatic carboxylic acid or heteroaromatic carboxylic acid, and (d) water, wherein the polishing composition has a pH of about 3 to about 6. The invention further provides a method of chemically mechanically polishing a substrate with the inventive chemical-mechanical polishing composition. Typically, the substrates contain silicon oxide.
1. A chemical-mechanical polishing composition comprising:
(a) wet-process ceria abrasive,
(b) a surfactant comprising an amine-containing anchor group and ethylene oxide-propylene oxide stabilizing group, wherein the surfactant has an average molecular weight of from about 1000 Daltons to about 5000 Daltons,
(c) an aromatic carboxylic acid or heteroaromatic carboxylic acid, and
(d) water,
wherein the polishing composition has a pH of about 3 to about 6.
2. The polishing composition of claim 1 , wherein the wet-process ceria abrasive is present in the polishing composition in an amount of from about 0.05 wt. % to about 2 wt. %.
3. The polishing composition of claim 1 , wherein the surfactant is a cationic comb polymer comprising an amine-containing anchor group of the formula:
wherein Ar is a 1,4-disubstituted arylene or
and n is an integer of from about 2 to about 10.
4. The polishing composition of claim 3 , wherein the ethylene oxide-propylene oxide stabilizing group has the formula: —(CH(CH 3 )CH 2 O) x (CH 2 CH 2 O) y CH 3 wherein x and y are independently selected integers of from about 2 to about 25.
5. The polishing composition of claim 1 , wherein the surfactant comprises one mono((diethylamino)alkyl) ether anchor group and one ethylene oxide-propylene oxide stabilizing group of the formula:
6. The polishing composition of claim 5 , wherein the ethylene oxide-propylene oxide stabilizing group has the formula: —C 2 H 4 (OCH 2 CH 2 ) x (OCH(CH 3 )CH 2 ) y OH wherein x and y are independently selected integers of from about 2 to about 25.
7. The polishing composition of claim 6 , wherein the ethylene oxide-propylene oxide stabilizing group has a ratio of ethylene oxide units to propylene oxide units of about 1:1 to about 1:3.
8. The polishing composition of claim 1 , wherein the surfactant is present in the polishing composition in an amount of about 10 ppm to about 500 ppm.
9. The polishing composition of claim 1 , wherein the aromatic carboxylic acid or heteroaromatic carboxylic acid is picolinic acid.
10. A method of chemically mechanically polishing a substrate comprising:
(i) providing a substrate,
(ii) providing a polishing pad,
(iii) providing a chemical-mechanical polishing composition comprising:
(a) wet-process ceria,
(b) a surfactant comprising an amine-containing anchor group and ethylene oxide-propylene oxide stabilizing group, wherein the surfactant has an average molecular weight of from about 1000 Daltons to about 5000 Daltons,
(c) an aromatic carboxylic acid or heteroaromatic carboxylic acid, and
(d) water,
wherein the polishing composition has a pH of about 3 to about 6,
(iv) contacting the substrate with the polishing pad and the chemical-mechanical polishing composition, and
(v) moving the polishing pad and the chemical-mechanical polishing composition relative to the substrate to abrade at least a portion of a surface of the substrate to polish the substrate.
11. The method of claim 10 , wherein the wet-process ceria abrasive is present in the polishing composition in an amount of from about 0.05 wt. % to about 2 wt. %.
12. The method of claim 10 , wherein the surfactant is a cationic comb polymer comprising an amine-containing anchor group of the formula:
wherein Ar is a 1,4-disubstituted arylene or
and n is an integer of from about 2 to about 10.
13. The method of claim 12 , wherein the ethylene oxide-propylene oxide stabilizing group has the formula: —(CH(CH 3 )CH 2 O) x (CH 2 CH 2 O) y CH 3 wherein x and y are independently selected integers of from about 2 to about 25.
14. The method of claim 10 , wherein the surfactant comprises one mono((diethylamino)alkyl) ether anchor group and one ethylene oxide-propylene oxide stabilizing group of the formula:
15. The method of claim 14 , wherein the ethylene oxide-propylene oxide stabilizing group has the formula: —C 2 H 4 (OCH 2 CH 2 ) x (OCH(CH 3 )CH 2 ) y OH wherein x and y are independently selected integers of from about 2 to about 25.
16. The method of claim 15 , wherein the ethylene oxide-propylene oxide stabilizing group has a ratio of ethylene oxide units to propylene oxide units of about 1:1 to about 1:3.
17. The method of claim 10 , wherein the surfactant is present in the polishing composition in an amount of about 10 ppm to about 500 ppm.
18. The method of claim 10 , wherein the aromatic carboxylic acid or heteroaromatic carboxylic acid is picolinic acid.
19. The method of claim 10 , wherein the substrate comprises silicon oxide, and wherein at least a portion of the silicon oxide is removed from the substrate to polish the substrate.