Granted Patent B2

US 12,215,044 · App. 17/530,907 · Granted Feb 4, 2025

Inventors: Carlos Borras (Apopka, FL); Donald A. Luke (Valrico, FL)

Assignee: NuQuatic, LLC

C02F1/46176C02F1/001C02F1/4676C02F1/5254C02F1/586C02F1/66C25B1/00C25B1/20C25B1/50C25B9/65C02F2001/46119C02F2001/46133C02F2101/105C02F2101/16C02F2101/20C02F2209/06

Abstract

Claims (50)

1. A system for removal of nitrogen and phosphorus from starting material water, the system comprising:

an elevated pH phosphorus removal stage configured to raise pH of the starting material water from less than 7.5 to greater than or equal to 7.5 via addition of one or more bases thereto in a mixing tank to precipitate a phosphorus salt from the starting material water and configured to remove the precipitated phosphorus salt from the starting material water, to form water from the elevated pH phosphorus removal stage;

an electrolytic nitrogen removal stage comprising an electrolytic cell configured to contact the water from the elevated pH phosphorus removal stage with the electrolytic cell to remove nitrogen therefrom as nitrogen gas, to form water from the electrolytic nitrogen removal stage; and

a galvanic phosphorus removal stage configured to contact the water from the electrolytic nitrogen removal stage with a galvanic cell to form a precipitate comprising a salt that comprises phosphorus, wherein the galvanic phosphorus removal stage is configured to separate the salt comprising the phosphorus from the treated water to form water from the galvanic phosphorus removal stage, wherein the galvanic cell comprises

an anode comprising Al, or a combination thereof,

a cathode having a different composition than the anode, the cathode comprising Cu, and

a conductive connector that electrically and physically connects the anode and the cathode, the conductive connector comprising Cu, Zn, Fe, Cd, Ni, Sn, Pb, or a combination thereof, wherein the conductive connector comprises a screw, a bolt, or a combination thereof;

wherein the water from the galvanic phosphorus removal stage has a lower phosphorus concentration and a lower nitrogen concentration than the starting material water.

2. The system of claim 1 , wherein the cathode comprises a porous cathode material.

3. The system of claim 1 , wherein the cathode comprises a porous cathode material comprising wire, mesh, screen, a sheet comprising one or more through-holes, or a combination thereof.

4. The system of claim 1 , wherein the cathode comprises a porous cathode material comprising a wire mesh or a wire screen.

5. The system of claim 1 , wherein the conductive connector comprises Cu and Zn.

6. The system of claim 1 , wherein the conductive connector comprises brass.

7. The system of claim 1 , wherein the system is configured for the starting material water having a chloride concentration of 200 ppm to 10,000 ppm.

8. The system of claim 1 , wherein the water from the galvanic phosphorus removal stage has a total phosphorus concentration, a dissolved phosphorus concentration, a reactive phosphorus concentration as measured according to US EPA Method 365.1, or a combination thereof, of 0.0001 ppm to 0.1 ppm, and a total nitrogen concentration, a dissolved nitrogen concentration, or a combination thereof, of about 0 ppm to about 1 ppm.

9. The system of claim 1 , wherein raising pH of the starting material water to precipitate the phosphorus salt therefrom comprises raising the pH of the starting material water to 8.5 to 9.5.

10. The system of claim 1 , wherein the precipitated phosphorus salt comprises struvite, calcium phosphate, or a combination thereof.

11. The system of claim 1 , wherein the electrolytic cell comprises a cathode comprising titanium, stainless steel, or a combination thereof.

12. The system of claim 1 , wherein the electrolytic cell comprises an anode comprising

titanium oxide, ruthenium oxide, and iridium oxide supported on titanium (TiO 2 —RuO 2 —IrO 2 /Ti), or

titanium oxide and ruthenium oxide supported on titanium (TiO 2 —RuO 2 /Ti), or

titanium and platinum (Ti—Pt), or

a combination thereof.

13. The system of claim 1 , wherein passing the water from the elevated pH phosphorus removal stage through the electrolytic nitrogen removal stage produces hypochlorite which reacts with ammonia in the water from the elevated pH phosphorus removal stage to form the nitrogen gas that is removed during the electrolytic nitrogen removal stage.

14. The system of claim 1 , wherein the salt comprising the phosphorus comprises a material from the anode of the galvanic cell.

15. The system of claim 1 , wherein the anode is about 90 wt % to about 100 wt % Al or Mg, and wherein the cathode is about 90 wt % to about 100 wt % Cu.

16. The system of claim 1 , wherein:

the water from the electrolytic nitrogen removal stage immersing the galvanic cell has a pH of about 5 to about 7;

the anode of the galvanic cell comprises Al, wherein the anode is about 90 wt % to about 100 wt % Al;

the cathode of the galvanic cell comprises Cu, wherein the cathode is about 90 wt % to about 100 wt % Cu;

the conductive connector comprises an alloy comprising Cu and Zn; and

the salt comprising the phosphorus formed in the galvanic phosphorus removal stage comprises

AlPO 4 or a hydrate thereof, the AlPO 4 comprising the phosphorus and Al from the anode,

aluminum hydroxide or a hydrate thereof, the aluminum hydroxide comprising Al from the anode, or

a combination thereof.

17. The system of claim 1 , wherein the elevated pH phosphorus removal stage is configured to remove 90-98% of reactive phosphorus in the starting material water as measured according to US EPA Method 365.1.

18. A system for removal of nitrogen and phosphorus from starting material water, the system comprising:

an elevated pH phosphorus removal stage configured to raise pH of the starting material water comprising both nitrogen and phosphorus to greater than or equal to 8.5 to 9.5 to precipitate a phosphorus salt from the water, the phosphorus salt comprising struvite, calcium phosphate, or a combination thereof, and configured to remove the precipitated phosphorus salt from the water, to form water from the elevated pH phosphorus removal stage, wherein the elevated pH phosphorus removal stage is configured to remove 90-98% of reactive phosphorus in the starting material water as measured according to US EPA Method 365.1;

an electrolytic nitrogen removal stage comprising an electrolytic cell configured to contact the water from the elevated pH phosphorus removal stage with the electrolytic cell to remove nitrogen therefrom as nitrogen gas, to form water from the electrolytic nitrogen removal stage, the electrolytic cell comprising a cathode comprising stainless steel and an anode that comprises titanium oxide, ruthenium oxide, and iridium oxide supported on titanium (TiO 2 —RuO 2 —IrO 2 /Ti), wherein passing the water from the elevated pH phosphorus removal stage through the electrolytic nitrogen removal stage removes 80-100% of ammonia therefrom; and

a galvanic phosphorus removal stage configured to contact the water from the electrolytic nitrogen removal stage with a galvanic cell to form a precipitate comprising a salt that comprises phosphorus, the salt comprising

AlPO 4 or a hydrate thereof, the AlPO 4 comprising the phosphorus and Al from the anode,

aluminum hydroxide or a hydrate thereof, the aluminum hydroxide comprising Al from the anode, or

a combination thereof,

wherein the galvanic phosphorus removal stage is configured to separate the salt comprising the phosphorus from the treated water to form water from the galvanic phosphorus removal stage, wherein the galvanic cell comprises

an anode comprising Al, wherein the anode is about 90 wt % to about 100 wt % Al,

a cathode having a different composition than the anode, the cathode comprising Cu, wherein the cathode is about 90 wt % to about 100 wt % Cu, and

a conductive connector that electrically and physically connects the anode and the cathode, the conductive connector comprising an alloy comprising Cu and Zn, wherein the conductive connector comprises a screw, a bolt, or a combination thereof;

wherein the water from the galvanic phosphorus removal stage has a lower phosphorus concentration and a lower nitrogen concentration than the starting material water, wherein the water from the galvanic phosphorus removal stage has

a total phosphorus concentration of about 0.0001 ppm to 0.05 ppm, and

a total nitrogen concentration of about 0 ppm to about 1 ppm.

Assignments (2)

Continuity (4)

References Cited (310)

Cited By (1)

US 12,492,137