IP Library › Granted Patent US 12,538,640
Granted Patent B2
US 12,538,640 · App. 17/841,930 · Granted Jan 27, 2026

Light-receiving device with buffer layer and light-emitting and light-receiving apparatus with buffer layer

Inventors: Yasuhiro Niikura (Tokyo, JP); Daisuke Kubota (Kanagawa, JP); Taisuke Kamada (Saitama, JP); Sachiko Kawakami (Kanagawa, JP); Anna Tada (Kanagawa, JP); Satoshi Seo (Kanagawa, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H10K50/16C07C15/20C07C15/28C07C15/38C07C211/54C07D209/82C07D219/16C07D221/20C07D235/08C07D251/24C07D307/91C07D333/18C07D333/76C07D401/10C07D403/10C07D403/14C07D405/04C07D405/12C07D409/10C07D409/12C07D409/14C07D413/10C07D471/06C07D471/14C07D491/048C07D495/04C07D495/14C07D495/22C07D519/00C07F7/2284C07F15/0093H10K30/20H10K65/00H10K85/30H10K85/346H10K85/615H10K85/622H10K85/623H10K85/624H10K85/631H10K85/652H10K85/654H10K85/656H10K85/657H10K85/6572H10K85/6574H10K85/6576H10K30/50
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Quick Facts
Patent No.
US 12,538,640
App. No.
17/841,930
Granted
Jan 27, 2026
Kind
B2
Abstract

A light-receiving device in which an increase in driving voltage is inhibited is provided. Any of the following light-receiving devices is provided: a light-receiving device that includes a light-receiving layer between a pair of electrodes and in which the light-receiving layer includes an active layer, a buffer layer, and an electron-transport layer, the buffer layer is between the active layer and the electron-transport layer and is in contact with the active layer, and the buffer layer includes an organic compound having an electron-withdrawing group; a light-receiving device that includes a light-receiving layer between a pair of electrodes and in which the light-receiving layer includes an active layer, a buffer layer, and an electron-transport layer, the buffer layer is between the active layer and the electron-transport layer and is in contact with the active layer, and the buffer layer includes a heteroaromatic compound having an electron-withdrawing group.

Claims (33)

1 . A light-receiving device comprising:

a light-receiving layer between a pair of electrodes,

wherein the light-receiving layer comprises an active layer, a buffer layer, and an electron-transport layer,

wherein the buffer layer is between the active layer and the electron-transport layer and is in contact with the active layer,

wherein the active layer comprises a first organic compound,

wherein the buffer layer comprises a second organic compound,

wherein the electron-transport layer comprises a third organic compound, and

wherein a LUMO level of the second organic compound is higher than a LUMO level of the first organic compound and is lower than a LUMO level of the third organic compound.

2 . The light-receiving device according to claim 1 ,

wherein a difference between the LUMO level of the second organic compound and the LUMO level of the first organic compound is less than or equal to 0.5 eV.

3 . The light-receiving device according to claim 1 ,

wherein a difference between the LUMO level of the second organic compound and the LUMO level of the third organic compound is less than or equal to 1.0 eV.

4 . The light-receiving device according to claim 1 ,

wherein the LUMO level of the second organic compound is higher than or equal to −4.5 eV and lower than or equal to −3.0 eV.

5 . A light-emitting and light-receiving apparatus comprising:

the light-receiving device according to claim 1 ; and

a light-emitting device.

6 . The light-receiving device according to claim 1 ,

wherein the second organic compound is a heteroaromatic compound comprising an electron-withdrawing group.

7 . The light-receiving device according to claim 6 ,

wherein the second organic compound comprises a plurality of cyano groups.

8 . The light-receiving device according to claim 6 ,

wherein the heteroaromatic compound comprises a fused heteroaromatic ring.

9 . The light-receiving device according to claim 1 ,

wherein the third organic compound is a T-electron deficient heteroaromatic compound.

10 . The light-receiving device according to claim 1 ,

wherein the third organic compound is one of a metal complex comprising a quinoline skeleton, a metal complex comprising a benzoquinoline skeleton, a metal complex comprising an oxazole skeleton, a metal complex comprising a thiazole skeleton, an oxadiazole derivative, a triazole derivative, an imidazole derivative, an oxazole derivative, a thiazole derivative, a phenanthroline derivative, a quinoline derivative comprising a quinoline ligand, a benzoquinoline derivative, a quinoxaline derivative, a dibenzoquinoxaline derivative, a pyridine derivative, a bipyridine derivative, and a pyrimidine derivative.

11 . The light-receiving device according to claim 1 ,

wherein the third organic compound is a compound comprising a triazine ring.

12 . The light-receiving device according to claim 1 ,

wherein the third organic compound is an organic compound represented by a general formula (Ge-1):

wherein Ar 1 to Ar 3 each independently represent one of hydrogen, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, and a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms, and

wherein X 1 and X 2 each independently represent one of carbon and nitrogen, and in the case where one or both of X 1 and X 2 is carbon, the carbon is bonded to one of hydrogen, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, and a substituted or unsubstituted cycloalkyl group having 1 to 20 carbon atoms.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 14, 2022
From: NIIKURA, YASUHIRO; KUBOTA, DAISUKE; KAMADA, TAISUKE; KAWAKAMI, SACHIKO; TADA, ANNA; SEO, SATOSHI
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 061085/0544 →
Priority Claims (2)
JP 2021-105667 · Jun 25, 2021 · national
JP 2021-105668 · Jun 25, 2021 · national
Continuity (1)
Related Publication 20230062265A1 · Mar 2, 2023
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