Compacted muriate of potash fertilizers containing micronutrients and methods of making same
A granular cohered MOP fertilizer having one or more micronutrients, and one or more binding ingredients. The fertilizer is prepared by compacting MOP feed material with a source of zinc and one or more optional binders to form a cohered MOP composition. The cohered MOP composition is then further processed, such as by crushing and sizing, to form a cohered granular MOP product containing a source of zinc. The process yields a fertilizer product containing micronutrients with superior elemental and granule size distribution without compromising handling or storage qualities.
1. A cohered and compacted potash fertilizer product comprising a plurality of fertilizer granules, each granule comprising:
a source of potassium chloride;
a source of zinc compacted with the source of potassium chloride, wherein the source of zinc provides zinc in an amount from about 0.001 to about 10 weight percent of the product; and
a phosphate-containing binding agent.
2. The product of claim 1 , wherein a source of the potassium chloride comprises MOP having a chemical profile of either 0-0-60 weight percent K 2 O or a 0-0-62 weight percent K 2 O based on a N—P 2 O 5 —K 2 O convention.
3. The product of claim 2 , wherein the MOP has a chemical profile of 0-0-60 weight percent K 2 O based on the N—P 2 O 5 —K 2 O convention.
4. The product of claim 3 , wherein the MOP has a chemical profile of 0-0-62 weight percent K 2 O based on the N—P 2 O 5 —K 2 O convention.
5. The product of claim 1 , wherein the source of zinc comprises zinc sulfate or zinc oxide.
6. The product of claim 5 , wherein the source of zinc comprises zinc sulfate.
7. The product of claim 5 , wherein the source of zinc comprises zinc oxide.
8. The product of claim 1 , wherein each granule further comprises, in addition to the source of zinc, a micronutrient or secondary nutrient selected from the group consisting of: boron (B), manganese (Mn), molybdenum (Mo), nickel (Ni), iron (Fe), copper (Cu), sulfur(S) in its elemental form, sulfur in its oxidized sulfate form (SO 4 ), and combinations thereof.
9. The product of claim 8 , wherein the micronutrient or secondary nutrient is present in the product in a range from about 0.001 to about 10 weight percent.
10. The product of claim 1 , wherein the zinc is present in an amount of about 0.001 weight percent to about 1.0 weight percent of the product.
11. The product of claim 1 , wherein the binding agent is selected from the group consisting of sodium hexametaphosphate (SHMP), tetra-sodium pyrophosphate (TSPP), tetra-potassium pyrophosphate (TKPP), sodium tri-polyphosphate (STPP); di-ammonium phosphate (DAP), mono-ammonium phosphate (MAP), granular mono-ammonium phosphate (GMAP), and combinations thereof.
12. A method of producing a cohered product containing micronutrients comprising:
combining potassium chloride, a phosphate-containing binding agent, and a source of zinc to form a composition, wherein the source of zinc is added in an amount such that the composition contains zinc in an amount of about 0.001 weight percent to about 10 weight percent;
compacting the composition; and
crushing the compacted composition into granules to produce the cohered product.
13. The method of claim 12 , wherein the method further comprises combining with the potassium, in addition to the source of zinc, a micronutrient or secondary nutrient selected from the group consisting of boron (B), manganese (Mn), molybdenum (Mo), nickel (Ni), copper (Cu), sulfur(S) in its elemental form, sulfur in its oxidized sulfate form (SO 4 ), and combinations thereof.
14. The method of claim 13 , wherein the source of zinc and the micronutrient or secondary nutrient are added to the potassium chloride as separate streams and blended with the potassium chloride before compaction.
15. The method of claim 13 , wherein the source of zinc and the micronutrient or secondary nutrient are blended in bulk before addition to the potassium chloride.
16. The method of claim 12 , further comprising:
classifying the granules of cohered product by size.
17. The method of claim 16 , wherein a size distribution of the granules is substantially uniform, and wherein granules which are non-conforming are resized until conformance.
18. The method of claim 12 , wherein the binding agent is selected from the group consisting of sodium hexametaphosphate (SHMP), tetra-sodium pyrophosphate (TSPP), tetra-potassium pyrophosphate (TKPP), sodium tri-polyphosphate (STPP); di-ammonium phosphate (DAP), mono-ammonium phosphate (MAP), granular mono-ammonium phosphate (GMAP), and combinations thereof.
19. The method of claim 12 , wherein the one or more micronutrients are present in the composition in a range from about 0.001 to about 10 weight percent.