IP Library Granted Patent US 9,617,450
Granted Patent B2
US 9,617,450 · App. 14/657,594 · Granted Apr 11, 2017

Polishing composition and method utilizing abrasive particles treated with an aminosilane

Inventors: Steven Grumbine (Aurora, IL); Shoutian Li (Naperville, IL); William Ward (Glen Ellyn, IL); Pankaj Singh (Plainfield, IL); Jeffrey Dysard (St. Charles, IL)
Assignee: Cabot Microelectronics Corporation
C09G1/02B24B37/044C09K3/1436C09K3/1463H01L21/31053
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Quick Facts
Patent No.
US 9,617,450
App. No.
14/657,594
Granted
Apr 11, 2017
Kind
B2
Abstract

The inventive method comprises chemically-mechanically polishing a substrate with an inventive polishing composition comprising a liquid carrier and abrasive particles that have been treated with a compound.

Claims (14)

1. A chemical-mechanical polishing composition for polishing a substrate comprising:

(i) a liquid carrier,

(ii) an abrasive suspended in the liquid carrier, wherein the abrasive comprises colloidal silica particles having a surface which has been treated with a compound selected from the group consisting of an aminosilane compound, a phosphononiumsilane compound, and a sulfonium silane compound, wherein the treated particles have a zeta potential of about 10 mV or more, and wherein the treated particles have a surface coverage of the available silanols of about 2% to about 50%, and

(iii) a phosphonic acid wherein the phosphonic acid is selected from the group consisting of amino tri(methylene phosphonic acid) and 1-hydroxyethylidene-1,1-diphosphonic acid, and

wherein the polishing composition has a pH of about 1.5 to about 5.

2. The polishing composition of claim 1 wherein the surface of the abrasive has been treated with an aminosilane compound that contains an aminopropyl group.

3. A chemical-mechanical polishing composition for polishing a substrate comprising:

(i) a liquid carrier,

(ii) an abrasive suspended in the liquid carrier, wherein the abrasive comprises metal oxide particles having a surface which has been treated with a compound selected from the group consisting of quaternary aminosilane compounds, dipodal aminosilane compounds, and combinations thereof, and wherein the treated particles have a surface coverage of the available silanols of about 2% to about 50%, and

(iii) an oxidizing agent, and

(iv) a corrosion inhibitor,

wherein the polishing composition has a pH of about 1.5 to about 5.

4. The polishing composition of claim 3 , wherein the abrasive is colloidal silica.

5. The polishing composition of claim 3 , wherein the polishing composition has a conductivity of about 1500 μS/cm or less.

Assignments (7)
CHANGE OF NAME Recorded Nov 22, 2023
From: CMC MATERIALS, INC.
To: CMC MATERIALS LLC
Reel/Frame 065663/0466 →
CHANGE OF NAME Recorded Nov 8, 2023
From: CMC MATERIALS, INC.
To: CMC MATERIALS LLC
Reel/Frame 065517/0783 →
SECURITY INTEREST Recorded Jul 8, 2022
From: CMC MATERIALS, INC.; INTERNATIONAL TEST SOLUTIONS, LLC; QED TECHNOLOGIES INTERNATIONAL, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
Reel/Frame 060615/0001 →
SECURITY INTEREST Recorded Jul 8, 2022
From: ENTEGRIS, INC.; ENTEGRIS GP, INC.; POCO GRAPHITE, INC.; CMC MATERIALS, INC.; INTERNATIONAL TEST SOLUTIONS, LLC; QED TECHNOLOGIES INTERNATIONAL, INC.
To: TRUIST BANK, AS NOTES COLLATERAL AGENT
Reel/Frame 060613/0072 →
RELEASE OF SECURITY INTEREST Recorded Jul 6, 2022
From: JPMORGAN CHASE BANK, N.A.
To: CABOT MICROELECTRONICS CORPORATION; QED TECHNOLOGIES INTERNATIONAL, INC.; FLOWCHEM LLC; KMG ELECTRONIC CHEMICALS, INC.; KMG-BERNUTH, INC.; MPOWER SPECIALTY CHEMICALS LLC; SEALWELD (USA), INC.; INTERNATIONAL TEST SOLUTIONS, LLC; CMC MATERIALS, INC.
Reel/Frame 060592/0260 →
CHANGE OF NAME Recorded Jan 13, 2021
From: CABOT MICROELECTRONICS CORPORATION
To: CMC MATERIALS, INC.
Reel/Frame 054980/0681 →
SECURITY AGREEMENT Recorded Nov 16, 2018
From: CABOT MICROELECTRONICS CORPORATION; QED TECHNOLOGIES INTERNATIONAL, INC.; FLOWCHEM LLC; KMG ELECTRONIC CHEMICALS, INC.; MPOWER SPECIALTY CHEMICALS LLC
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 047588/0263 →
Continuity (3)
Division 12234237 · Sep 19, 2008
Provisional Application 60974328 · Sep 21, 2007
Related Publication 20150184029A1 · Jul 2, 2015