Cobalt polishing accelerators
View Patent ↗The invention provides a chemical-mechanical polishing composition comprising (a) abrasive particles, (b) a cobalt accelerator selected from a compound having the formula: NR 1 R 2 R 3 wherein R 1 , R 2 , and R 3 are independently selected from hydrogen, carboxyalkyl, substituted carboxyalkyl, hydroxyalkyl, substituted hydroxyalkyl and aminocarbonylalkyl, wherein none or one of R 1 , R 2 , and R 3 are hydrogen; dicarboxyheterocycles; heterocyclylalkyl-α-amino acids; N-(amidoalkyl)amino acids; unsubstituted heterocycles; alkyl-substituted heterocycles; substituted-alkyl-substituted heterocycles; N-aminoalkyl-α-amino acids; and combinations thereof, (c) a cobalt corrosion inhibitor, (d) an oxidizing agent that oxidizes a metal, and (e) water, wherein the polishing composition has a pH of about 3 to about 8.5. The invention further provides a method of chemically-mechanically polishing a substrate with the inventive chemical-mechanical polishing composition. Typically, the substrate contains cobalt.
1. A chemical-mechanical polishing composition comprising:
(a) abrasive particles,
(b) a cobalt accelerator selected from a compound having the formula: NR 1 R 2 R 3 wherein R 1 , R 2 , and R 3 are independently selected from hydrogen, carboxyalkyl, substituted carboxyalkyl, hydroxyalkyl, substituted hydroxyalkyl and aminocarbonylalkyl, wherein none or one of R 1 , R 2 , and R 3 are hydrogen; dicarboxyheterocycles; heterocyclylalkyl-α-amino acids; N-(amidoalkyl)amino acids; unsubstituted heterocycles; alkyl-substituted heterocycles; substituted-alkyl-substituted heterocycles; N-aminoalkyl-α-amino acids; and combinations thereof,
(c) a cobalt corrosion inhibitor, wherein the cobalt corrosion inhibitor comprises an anionic head group and a C 8 -C 14 aliphatic tail group,
(d) an oxidizing agent that oxidizes cobalt, and
(e) water,
wherein the polishing composition has a pH of about 3 to about 8.5.
2. The polishing composition of claim 1 , wherein the polishing composition comprises about 0.1 wt. % to about 2 wt. % of abrasive particles.
3. The polishing composition of claim 1 , wherein the cobalt accelerator is selected from iminodiacetic acid, picolinic acid, dipicolinic acid, bicine, [(2-amino-2-oxoethyl)amino]acetic acid, lysine, imidazole, histidine, 2-[bis(2-hydroxyethyl) amino]-2-(hydroxymethyl)-1,3-propanediol, and combinations thereof.
4. The polishing composition of claim 1 , wherein the cobalt accelerator is present in the polishing composition in a concentration of about 5 mM to about 100 mM.
5. The polishing composition of claim 1 , wherein the cobalt corrosion inhibitor has the formula: RCON(CH 3 )COOH wherein R is a C 8 -C 13 aliphatic group.
6. The polishing composition of claim 1 , wherein the polishing composition comprises about 10 ppm to about 1000 ppm of the cobalt corrosion inhibitor.
7. The polishing composition of claim 1 , wherein the oxidizing agent is hydrogen peroxide.
8. The polishing composition of claim 1 , wherein the polishing composition has a pH of about 7 to about 8.