Granted Patent
B2
US 12,308,421 · App. 15/698,695 · Granted May 20, 2025
Electrode and power storage device comprising graphene compound
Inventors:
Mayumi Mikami (Kanagawa, JP); Yohei Momma (Kanagawa, JP); Minoru Takahashi (Nagano, JP); Hiroshi Kadoma (Kanagawa, JP); Teppei Oguni (Kanagawa, JP); Satoshi Seo (Kanagawa, JP)
H01M4/366C07F7/12C07F7/1804H01G11/26H01G11/30H01G11/36H01G11/38H01G11/46H01G11/50H01M4/131H01M4/505H01M4/525H01M4/625H01M10/052H01M10/0525H01M10/4235H01G11/06H01G11/42H01G11/52H01G11/58H01M2220/20Y02E60/10
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Abstract
A novel electrode, a novel power storage device, an electrode with less deterioration, an electrode with a high capacity, a long-life power storage device, a power storage device with less deterioration, a power storage device with high energy density, or a highly reliable power storage device is provided. The electrode includes a graphene compound including a graphene layer and a substituted or unsubstituted chain group, and an active material. The graphene layer is bonded to the chain group through a substituent containing silicon. The graphene compound includes a region in contact with the active material in particle form. The active material includes an element A, which is one or more elements selected from elements belonging to Group 1 and elements belonging to Group 2, and an element M, which is one or more elements selected from manganese and nickel. The chain group includes one or more groups selected from a carbonyl group, an ester group, a carboxyl group, an ether group, and an epoxy group.
Claims (56)
1. A power storage device comprising:
a positive electrode; and
a negative electrode over the positive electrode,
wherein the positive electrode comprises:
a current collector;
an active material layer over and in contact with the current collector; and
a layer over and in contact with the active material layer,
wherein the active material layer comprises an active material and a conductive additive,
wherein the layer comprises a graphene compound,
wherein the active material comprises an element A and an element M,
wherein the element A is one or more elements selected from elements belonging to Group 1 and elements belonging to Group 2,
wherein the element M is one or more elements selected from manganese and nickel,
wherein the graphene compound has a structure represented by a following formula (G1):
wherein G layer represents a graphene layer,
wherein R 1 represents a substituted alkylene group,
wherein R 2 represents a substituted or unsubstituted alkyl group, and
wherein the substituted alkylene group comprises a substituent selected from an alkyl group having 1 to 6 carbon atoms, an aryl group having 6 to 10 carbon atoms, fluorine, and trifluoromethane.
2. The power storage device according to claim 1 ,
wherein the substituted alkylene group comprises an alkylene group having 1 to 20 carbon atoms.
3. The power storage device according to claim 2 ,
wherein the substituted alkylene group comprises an alkylene group having 1 to 11 carbon atoms.
4. The power storage device according to claim 1 ,
wherein the graphene compound is capable of trapping the element M.
5. The power storage device according to claim 1 , further comprising:
an exterior; and
an electrolyte solution.
6. The power storage device according to claim 1 ,
wherein the substituted alkylene group comprises the substituent selected from a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, an n-hexyl group, a phenyl group, an o-tolyl group, an m-tolyl group, a p-tolyl group, a 1-naphthyl group, a 2-naphthyl group, fluorine, and trifluoromethane.
7. A power storage device comprising:
a positive electrode; and
a negative electrode over the positive electrode,
wherein the positive electrode comprises:
a current collector;
an active material layer over and in contact with the current collector; and
a layer over and in contact with the active material layer,
wherein the active material layer comprises an active material and a conductive additive,
wherein the layer comprises a graphene compound,
wherein the active material comprises an element A and an element M,
wherein the element A is one or more elements selected from elements belonging to Group 1 and elements belonging to Group 2,
wherein the element M is one or more elements selected from manganese and nickel,
wherein the graphene compound has a structure represented by a following formula (G2):
wherein G layer represents a graphene layer,
wherein R 1 represents a substituted alkylene group,
wherein R 2 represents hydrogen or a substituted or unsubstituted alkyl group, and
wherein the substituted alkylene group comprises a substituent selected from an alkyl group having 1 to 6 carbon atoms, an aryl group having 6 to 10 carbon atoms, fluorine, and trifluoromethane.
8. The power storage device according to claim 7 ,
wherein the substituted alkylene group comprises an alkylene group having 1 to 20 carbon atoms.
9. The power storage device according to claim 8 ,
wherein the substituted alkylene group comprises an alkylene group having 1 to 11 carbon atoms.
10. The power storage device according to claim 7 ,
wherein the graphene compound is capable of trapping the element M.
11. The power storage device according to claim 7 , further comprising:
an exterior; and
an electrolyte solution.
12. The power storage device according to claim 7 ,
wherein the substituted alkylene group comprises the substituent selected from a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, an n-hexyl group, a phenyl group, an o-tolyl group, an m-tolyl group, a p-tolyl group, a 1-naphthyl group, a 2-naphthyl group, fluorine, and trifluoromethane.
Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST
Recorded Sep 8, 2017
From: MIKAMI, MAYUMI; MOMMA, YOHEI; TAKAHASHI, MINORU; KADOMA, HIROSHI; OGUNI, TEPPEI; SEO, SATOSHI
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 043528/0786 →
Priority Claims (1)
JP 2016-177284
· Sep 12, 2016
· national
Continuity (1)
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