Granted Patent
B2
US 12,459,175 · App. 18/450,568 · Granted Nov 4, 2025
Injection-molded body and production method therefor
Inventors:
Hiroyuki Hamada (Osaka, JP); Tadaharu Isaka (Osaka, JP); Hayato Tsuda (Osaka, JP); Yumi Zenke (Osaka, JP); Yukari Yamamoto (Osaka, JP); Yasuyuki Yamaguchi (Osaka, JP)
Assignee:
DAIKIN INDUSTRIES, LTD.
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Abstract
Provided is an injection molded article containing a copolymer containing tetrafluoroethylene unit and a fluoro(alkyl vinyl ether) unit, wherein the content of the fluoro(alkyl vinyl ether) unit of the copolymer is 3.9 to 4.8% by mass with respect to the whole of the monomer units, the melt flow rate at 372° C. of the copolymer is 11.0 to 19.0 g/10 min, the melting point of the copolymer is 296 to 305° C., and the amount of fluorine ions dissolving out from the injection molded article into water is 7,500 μg/m 2 or lower.
Claims (15)
1 . An injection molded article comprising a copolymer comprising tetrafluoroethylene unit and a fluoro(alkyl vinyl ether) unit,
wherein a content of the fluoro(alkyl vinyl ether) unit of the copolymer is 3.9 to 4.8% by mass with respect to the whole of the monomer units,
a melt flow rate at 372° C. of the copolymer is 11.0 to 19.0 g/10 min,
a melting point of the copolymer is 296 to 305° C., and
an amount of fluorine ions dissolving out from the injection molded article into water is 7,500 μg/m 2 or lower.
2 . The injection molded article according to claim 1 , wherein the amount of fluorine ions dissolving out from the injection molded article into water is 5,500 μg/m 2 or lower.
3 . The injection molded article according to claim 1 , wherein an amount of metal dissolving out from the injection molded article into 50% by mass hydrofluoric acid is 200 μg/m 2 or lower.
4 . The injection molded article according to claim 1 , wherein the fluoro(alkyl vinyl ether) unit of the copolymer is perfluoro(propyl vinyl ether) unit.
5 . The injection molded article according to claim 1 , wherein the content of the fluoro(alkyl vinyl ether) unit of the copolymer is 4.1 to 4.5% by mass with respect to the whole of the monomer units.
6 . The injection molded article according to claim 1 , wherein the melt flow rate at 372° C. of the copolymer is 12.0 to 17.6 g/10 min.
7 . The injection molded article according to claim 1 , wherein the total number of —CF═CF 2 , —CF 2 H, —COF, —COOH, —COOCH 3 , —CONH 2 and —CH 2 OH of the copolymer is 20 or less per 10 6 main-chain carbon atoms.
8 . The injection molded article according to claim 1 , wherein the injection molded article is a female joint.
9 . A method for producing the injection molded article according to claim 1 , comprising injection molding the copolymer using an injection molding machine provided with a cylinder and a screw accommodated in the cylinder, to obtain the injection molded article.
10 . The production method according to claim 9 , wherein the temperature of the copolymer in the cylinder is adjusted to 385 to 395° C.
11 . The production method according to claim 9 , wherein a Ni plated cylinder or a cylinder formed of a Ni-based alloy is used as the cylinder, and a screw formed of a Ni-based alloy and provided with a smear head on a head end is used as the screw.
Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST
Recorded Aug 16, 2023
From: HAMADA, HIROYUKI; ISAKA, TADAHARU; TSUDA, HAYATO; ZENKE, YUMI; YAMAMOTO, YUKARI; YAMAGUCHI, YASUYUKI
To: DAIKIN INDUSTRIES, LTD.
Reel/Frame 064608/0025 →
Priority Claims (5)
JP 2021-031087
· Feb 26, 2021
· national
JP 2021-031090
· Feb 26, 2021
· national
JP 2021-031091
· Feb 26, 2021
· national
JP 2021-031094
· Feb 26, 2021
· national
JP 2021-162163
· Sep 30, 2021
· national
Continuity (2)
Continuation
PCTJP2022003661
· Jan 31, 2022
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