IP Library Granted Patent US 9,067,297
Granted Patent B2
US 9,067,297 · App. 13/306,845 · Granted Jun 30, 2015

Polishing pad with foundation layer and polishing surface layer

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Quick Facts
Patent No.
US 9,067,297
App. No.
13/306,845
Granted
Jun 30, 2015
Kind
B2
Abstract

Polishing pads with foundation layers and polishing surface layers are described. In an example, a polishing pad for polishing a substrate includes a foundation layer. A polishing surface layer is bonded to the foundation layer. Methods of fabricating polishing pads with a polishing surface layer bonded to a foundation layer are also described.

Claims (98)

1. A polishing pad for polishing a substrate, the polishing pad comprising:

a foundation layer having a first hardness; and

a polishing surface layer bonded directly to the foundation layer, the polishing surface layer having a second hardness less than the first hardness, wherein the polishing surface layer is covalently bonded to the foundation layer.

2. The polishing pad of claim 1 , wherein the polishing surface layer comprises a continuous layer portion with a plurality of polishing features protruding there from, the continuous layer portion bonded directly to the foundation layer.

3. The polishing pad of claim 1 , wherein the polishing surface layer. comprises a plurality of discrete polishing protrusions bonded directly to the foundation layer.

4. The polishing pad of claim 1 , wherein the foundation layer and the polishing surface layer have a peel resistance sufficient to withstand a shear force applied during the useful lifetime of the polishing pad.

5. The polishing pad of claim 1 , wherein the foundation layer has a surface roughness greater than approximately 1 micrometer Ra (root mean square) where the polishing surface layer is bonded directly to the foundation layer.

6. The polishing pad of claim 5 , wherein the surface roughness is approximately in the range of 5-10 micrometers Ra (root mean square).

7. The polishing pad of claim 1 , wherein the foundation layer has a smooth surface with a surface roughness less than approximately 1 micrometer Ra (root mean square) where the polishing surface layer is bonded directly to the foundation layer.

8. The polishing pad of claim 7 , wherein the polishing surface layer. comprises a material formed from polyurethane.

9. The polishing pad of claim 1 , wherein the foundation layer has an energy loss factor of less than approximately 100 KEL at 1/Pa at 40° C.

10. The polishing pad of claim 1 , wherein the foundation layer has a compressibility of less than approximately 1% under a central pressure of 5 PSI.

11. The polishing pad of claim 1 , wherein the foundation layer has a hardness greater than approximately 75 Shore D.

12. The polishing pad of claim 1 , wherein the foundation layer comprises a polycarbonate material.

13. The polishing pad of claim 1 , wherein the foundation layer comprises a material selected from the group consisting of an epoxy board material and a metal sheet.

14. The polishing pad of claim 1 , wherein the polishing surface layer has an energy loss factor of greater than approximately 1000 KEL at 1/Pa at 40° C.

15. The polishing pad of claim 1 , wherein the polishing surface layer has a compressibility of greater than approximately 0.1% under a central pressure of 5 PSI.

16. The polishing pad of claim 1 , wherein the polishing surface layer has a hardness less than approximately 70 Shore D.

17. The polishing pad of claim 1 , wherein the polishing surface layer is a homogeneous polishing surface layer.

18. The polishing pad of claim 17 , wherein the homogeneous polishing surface layer comprises a thermoset polyurethane material.

19. The polishing pad of claim 1 , wherein the polishing surface layer has a pore density of closed cell pores approximately in the range of 6% -50% total void volume.

20. The polishing pad of claim 1 , wherein the foundation layer has an energy loss factor of less than approximately 100 KEL at 1/Pa at 40° C., wherein the polishing surface layer has an energy loss factor of greater than approximately 1000 KEL at 1/Pa at 40° C., and wherein the foundation layer and the polishing surface layer together have an energy loss factor of less than approximately 100 KEL at 1/Pa at 40° C.

21. The polishing pad of claim 1 , wherein the foundation layer has a hardness approximately in the range of 70 - 90 Shore D, and the polishing surface layer has a hardness approximately in the range of 50 - 60 Shore D.

22. The polishing pad of claim 1 , wherein the foundation layer has a hardness approximately in the range of 70 - 90 Shore D, and the polishing surface layer has a hardness approximately in the range of 20 - 50 Shore D.

23. The polishing pad of claim 1 , wherein the polishing surface layer has a first modulus of elasticity, and the foundation layer has a second modulus of elasticity greater than approximately 10 times the first modulus of elasticity.

24. The polishing pad of claim 23 , wherein the polishing surface layer has a first modulus of elasticity, and the foundation layer has a second modulus of elasticity greater than approximately 100 times the first modulus of elasticity.

25. The polishing pad of claim 1 , wherein the polishing surface layer has a thickness approximately in the range of 2 - 50 mils, and the foundation layer has a thickness of greater than approximately 20 mils.

26. The polishing pad of claim 25 , wherein the thickness of the foundation layer is greater than the thickness of the polishing surface layer.

27. The polishing pad of claim 1 , wherein the foundation layer has a thickness and hardness relative to the thickness and hardness of the polishing surface layer sufficient to dictate the bulk polishing characteristics of the polishing pad.

28. The polishing pad of claim 1 , wherein the foundation layer is sufficiently thick for the polishing pad to provide die-level polishing planarity, but sufficiently thin for the polishing pad to provide wafer-level polishing uniformity.

29. The polishing pad of claim 1 , further comprising:

a detection region disposed in the foundation layer.

30. The polishing pad of claim 1 , further comprising:

an aperture disposed in the polishing pad, through the polishing surface layer and the foundation layer; and

an adhesive sheet disposed on a back surface of the foundation layer but not in the aperture, the adhesive sheet providing an impermeable seal for the aperture at the back surface of the foundation layer.

31. The polishing pad of claim 1 , further comprising:

a sub pad having a third hardness less than the first hardness, wherein the foundation layer is disposed proximate to the sub pad.

32. The polishing pad of claim 31 , wherein the foundation layer has a hardness approximately in the range of 70 - 90 Shore D, the polishing surface layer has a hardness approximately in the range of 20 60 Shore D, and the sub pad has a hardness less than approximately 90 Shore A.

33. The polishing pad of claim 31 , wherein the polishing pad provides die-level polishing planarity and wafer-level polishing uniformity.

34. The polishing pad of claim 1 , wherein the foundation layer comprises a stack of sub layers.

35. A polishing pad for polishing a substrate, the polishing pad comprising:

a foundation layer having a first hardness; and

a polishing surface layer bonded directly to the foundation layer, the polishing surface layer having a second hardness equal to or greater than the first hardness, wherein the polishing surface layer comprises a continuous layer portion with plurality of polishing features protruding there from, the continuous layer portion covalently bonded directly to the foundation layer.

36. The polishing pad of claim 35 , wherein the foundation layer and the polishing surface layer have a peel resistance sufficient to withstand a shear force applied during the useful lifetime of the polishing pad.

37. A polishing pad for polishing a substrate, the polishing pad comprising:

a foundation layer having a first hardness; and

a polishing surface layer bonded directly to the foundation layer, the polishing surface layer having a second hardness less than the first hardness, wherein the polishing surface layer comprises a plurality of discrete polishing protrusions bonded directly to the foundation layer.

38. The polishing pad of claim 37 , wherein the foundation layer and the polishing surface layer have a peel resistance sufficient to withstand a shear force applied during the useful lifetime of the polishing pad.

39. The polishing pad of claim 37 , wherein the foundation layer has a surface roughness greater than approximately 1 micrometer Ra (root mean square) where the polishing surface layer is bonded directly to the foundation layer.

40. The polishing pad of claim 39 , wherein the surface roughness is approximately in the range of 5 - 10 micrometers Ra (root mean square).

41. The polishing pad of claim 37 , wherein the foundation layer has a smooth surface with a surface roughness less than approximately 1 micrometer Ra (root mean square) where the polishing surface layer is bonded directly to the foundation layer.

42. The polishing pad of claim 41 , wherein the polishing surface layer comprises a material formed from polyurethane.

43. The polishing pad of claim 37 , wherein the foundation layer has an energy loss factor of less than approximately 100 KEL at 1/Pa at 40° C.

44. The polishing pad of claim 37 , wherein the foundation layer has a compressibility of less than approximately 1% under a central pressure of 5 PSI.

45. The polishing pad of claim 37 , wherein the foundation layer has a hardness greater than approximately 75 Shore D.

46. The polishing pad of claim 37 , wherein the foundation layer comprises a polycarbonate material.

47. The polishing pad of claim 37 , wherein the foundation layer comprises a material selected from the group consisting of an epoxy board material and a metal sheet.

48. The polishing pad of claim 37 , wherein the polishing surface layer has an energy loss factor of greater than approximately 1000 KEL at 1/Pa at 40° C.

49. The polishing pad of claim 37 , wherein the polishing surface layer has a compressibility of greater than approximately 0.1% under a central pressure of 5 PSI.

50. The polishing pad of claim 37 , wherein the polishing surface layer has a hardness less than approximately 70 Shore D.

51. The polishing pad of claim 37 , wherein the polishing surface layer is a homogeneous polishing surface layer.

52. The polishing pad of claim 51 , wherein the homogeneous polishing surface layer comprises a thermoset polyurethane material.

53. The polishing pad of claim 37 , wherein the polishing surface layer has a pore density of closed cell pores approximately in the range of 6% - 50% total void volume.

54. The polishing pad of claim 37 , wherein the foundation layer has an energy loss factor of less than approximately 100 KEL at 1/Pa at 40° C., wherein the polishing surface layer has an energy loss factor of greater than approximately 1000 KEL at 1/Pa at 40° C., and wherein the foundation layer and the polishing surface layer together have an energy loss factor of less than approximately 100 KEL at 1/Pa at 40° C.

55. The polishing pad of claim 37 , wherein the foundation layer has a hardness approximately in the range of 70 - 90 Shore D, and the polishing surface layer has a hardness approximately in the range of 50 - 60 Shore D.

56. The polishing pad of claim 37 , wherein the foundation layer has a hardness approximately in the range of 70 - 90 Shore D, and the polishing surface layer has a hardness approximately in the range of 20 - 50 Shore D.

57. The polishing pad of claim 37 , wherein the polishing surface layer has a first modulus of elasticity, and the foundation layer has a second modulus of elasticity greater than approximately 10 times the first modulus of elasticity.

58. The polishing pad of claim 57 , wherein the polishing surface layer has a first modulus of elasticity, and the foundation layer has a second modulus of elasticity greater than approximately 100 times the first modulus of elasticity.

59. The polishing pad of claim 37 , wherein the polishing surface layer has a thickness approximately in the range of 2 - 50 mils, and the foundation layer has a thickness of greater than approximately 20 mils.

60. The polishing pad of claim 59 , wherein the thickness of the foundation layer is greater than the thickness of the polishing surface layer.

61. The polishing pad of claim 37 , wherein the foundation layer has a thickness and hardness relative to the thickness and hardness of the polishing surface layer sufficient to dictate the bulk polishing characteristics of the polishing pad.

62. The polishing pad of claim 37 , wherein the foundation layer is sufficiently thick for the polishing pad to provide die-level polishing planarity, but sufficiently thin for the polishing pad to provide wafer-level polishing uniformity.

63. A polishing pad for polishing a substrate, the polishing pad comprising:

a foundation layer having a first hardness; and

a polishing surface layer bonded directly to the foundation layer, the polishing surface layer having a second hardness less than the first hardness, wherein the foundation layer has a surface roughness greater than approximately 1 micrometer Ra (root mean square) where the polishing surface layer is bonded directly to the foundation layer.

64. The polishing pad of claim 63 , wherein the polishing surface layer comprises a continuous layer portion with a plurality of polishing features protruding there from, the continuous layer portion bonded directly to the foundation layer.

65. The polishing pad of claim 63 , wherein the foundation layer and the polishing surface layer have a peel resistance sufficient to withstand a shear force applied during the useful lifetime of the polishing pad.

66. The polishing pad of claim 63 , wherein the surface roughness is approximately in the range of 5 - 10 micrometers Ra (root mean square).

67. The polishing pad of claim 63 , wherein the foundation layer has an energy loss factor of less than approximately 100 KEL at 1/Pa at 40° C.

68. The polishing pad of claim 63 , wherein the foundation layer has a compressibility of less than approximately 1% under a central pressure of 5 PSI.

69. The polishing pad of claim 63 , wherein the foundation layer comprises a polycarbonate material.

70. A polishing pad for polishing a substrate, the polishing pad comprising:

a foundation layer having a first hardness; and

a polishing surface layer bonded directly to the foundation layer, the polishing surface layer having a second hardness less than the first hardness, wherein the foundation layer has a smooth surface with a surface roughness less than approximately 1 micrometer Ra (root mean square) where the polishing surface layer is bonded directly to the foundation layer.

71. The polishing pad of claim 70 , wherein the polishing surface layer comprises a continuous layer portion with a plurality of polishing features protruding there from, the continuous layer portion bonded directly to the foundation layer.

72. The polishing pad of claim 70 , wherein the foundation layer and the polishing surface layer have a peel resistance sufficient to withstand a shear force applied during the useful lifetime of the polishing pad.

73. The polishing pad of claim 70 , wherein the foundation layer has an energy loss factor of less than approximately 100 KEL at 1/Pa at 40° C.

74. The polishing pad of claim 70 , wherein the foundation layer has a compressibility of less than approximately 1% under a central pressure of 5 PSI.

75. The polishing pad of claim 70 , wherein the foundation layer comprises a polycarbonate material.

76. A polishing pad for polishing a substrate, the polishing pad comprising:

a foundation layer having a first hardness; and

a polishing surface layer bonded directly to the foundation layer, the polishing surface layer having a second hardness less than the first hardness, wherein the foundation layer has an energy loss factor of less than approximately 100 KEL at 1/Pa at 40° C., wherein the polishing surface layer has an energy loss factor of greater than approximately 1000 KEL at 1/Pa at 40° C., and wherein the foundation layer and the polishing surface layer together have an energy loss factor of less than approximately 100 KEL at 1/Pa at 40° C.

77. The polishing pad of claim 76 , wherein the polishing surface layer comprises a continuous layer portion with a plurality of polishing features protruding there from, the continuous layer portion bonded directly to the foundation layer.

78. The polishing pad of claim 76 , wherein the foundation layer and the polishing surface layer have a peel resistance sufficient to withstand a shear force applied during the useful lifetime of the polishing pad.

79. The polishing pad of claim 76 , wherein the foundation layer has a surface roughness greater than approximately 1 micrometer Ra (root mean square) where the polishing surface layer is bonded directly to the foundation layer.

80. The polishing pad of claim 76 , wherein the foundation layer has a smooth surface with a surface roughness less than approximately 1 micrometer Ra (root mean square) where the polishing surface layer is bonded directly to the foundation layer.

81. The polishing pad of claim 76 , wherein the foundation layer has a compressibility of less than approximately 1% under a central pressure of 5 PSI.

82. The polishing pad of claim 76 , wherein the foundation layer comprises a polycarbonate material.

Assignments (11)
CHANGE OF NAME Recorded Nov 22, 2023
From: CMC MATERIALS, INC.
To: CMC MATERIALS LLC
Reel/Frame 065663/0466 →
CHANGE OF NAME Recorded Nov 8, 2023
From: CMC MATERIALS, INC.
To: CMC MATERIALS LLC
Reel/Frame 065517/0783 →
SECURITY INTEREST Recorded Jul 8, 2022
From: ENTEGRIS, INC.; ENTEGRIS GP, INC.; POCO GRAPHITE, INC.; CMC MATERIALS, INC.; INTERNATIONAL TEST SOLUTIONS, LLC; QED TECHNOLOGIES INTERNATIONAL, INC.
To: TRUIST BANK, AS NOTES COLLATERAL AGENT
Reel/Frame 060613/0072 →
SECURITY INTEREST Recorded Jul 8, 2022
From: CMC MATERIALS, INC.; INTERNATIONAL TEST SOLUTIONS, LLC; QED TECHNOLOGIES INTERNATIONAL, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
Reel/Frame 060615/0001 →
RELEASE OF SECURITY INTEREST Recorded Jul 6, 2022
From: JPMORGAN CHASE BANK, N.A.
To: CABOT MICROELECTRONICS CORPORATION; QED TECHNOLOGIES INTERNATIONAL, INC.; FLOWCHEM LLC; KMG ELECTRONIC CHEMICALS, INC.; KMG-BERNUTH, INC.; MPOWER SPECIALTY CHEMICALS LLC; SEALWELD (USA), INC.; INTERNATIONAL TEST SOLUTIONS, LLC; CMC MATERIALS, INC.
Reel/Frame 060592/0260 →
CHANGE OF NAME Recorded Jan 13, 2021
From: CABOT MICROELECTRONICS CORPORATION
To: CMC MATERIALS, INC.
Reel/Frame 054980/0681 →
RELEASE OF SECURITY INTEREST Recorded Nov 16, 2018
From: BANK OF AMERICA, N.A.
To: CABOT MICROELECTRONICS CORPORATION; NEXPLANAR CORPORATION
Reel/Frame 047586/0400 →
SECURITY AGREEMENT Recorded Nov 16, 2018
From: CABOT MICROELECTRONICS CORPORATION; QED TECHNOLOGIES INTERNATIONAL, INC.; FLOWCHEM LLC; KMG ELECTRONIC CHEMICALS, INC.; MPOWER SPECIALTY CHEMICALS LLC
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 047588/0263 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 19, 2017
From: NEXPLANAR CORPORATION
To: CABOT MICROELECTRONICS CORPORATION
Reel/Frame 043046/0377 →
INTELLECTUAL PROPERTY SECURITY JOINDER AGREEMENT Recorded Dec 31, 2015
From: NEXPLANAR CORPORATION
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 037407/0071 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 15, 2012
From: ALLISON, WILLIAM C.; SCOTT, DIANE; LEFEVRE, PAUL ANDRE; LACASSE, JAMES P.; SIMPSON, ALEXANDER WILLIAM
To: NEXPLANAR CORPORATION
Reel/Frame 027711/0719 →