Granted Patent B2

US 12,351,492 · App. 17/554,229 · Granted Jul 8, 2025

Inventors: Carlos Borras (Ruskin, FL); Donald A. Luke (Valrico, FL)

Assignee: NuQuatic, LLC

C02F1/46109C02F1/46176C02F2001/46133C02F2001/46152C02F2101/105

Abstract

Claims (33)

1. A method of removing phosphorus from water, the method comprising:

immersing an electrochemical cell in water comprising phosphorus to form treated water comprising a salt that comprises the phosphorus, the electrochemical cell comprising

an anode comprising Mg, Al, Fe, Zn, or a combination thereof, wherein the anode comprises a planar nonporous form,

a cathode having a different composition than the anode, the cathode comprising Cu, Ni, Fe, or a combination thereof, wherein the cathode comprises a wire mesh, wherein the cathode is arranged parallel to a major face of the planar nonporous form of the anode such that a gap is formed between the major face of the planar nonporous form of the anode and the cathode, and

at least one conductive connector connecting the cathode to the anode, wherein the conductive connector maintains the gap between the cathode and the major face of the planar nonporous form of the anode; and

separating the salt comprising the phosphorus from the treated water, to form separated water having a lower phosphorus concentration than the water comprising phosphorus.

2. The method of claim 1 , wherein the electrochemical cell is a galvanic cell.

3. The method of claim 1 , wherein the conductive connector comprises Cu, Zn, Fe, Cd, Ni, Sn, Pb, or a combination thereof.

4. The method of claim 3 , wherein the conductive connector comprises brass.

5. The method of claim 3 , wherein the conductive connector comprises a weld, a fastener, a fastener assembly, a threaded fastener, a screw, a bolt, a bracket, a nut, a washer, or a combination thereof.

6. The method of claim 3 , wherein the conductive connector maintains a gap between the cathode and the anode.

7. The method of claim 1 , wherein the salt comprising the phosphorus comprises a material from the anode.

8. The method of claim 1 , wherein the cathode comprises Cu and the anode comprises Mg.

9. The method of claim 1 , wherein the cathode comprises Cu and the anode comprises Al.

10. The method of claim 1 , further comprising adding hydrogen peroxide to the water comprising phosphorus such that the comprising phosphorus comprises the hydrogen peroxide while the electrochemical cell is immersed in the water comprising the phosphorus, comprising adding 0.1 ppm to 1000 ppm of hydrogen peroxide to the water comprising phosphorus.

11. The method of claim 1 ,

wherein the cathode is a first cathode and the gap is a first gap, wherein the electrochemical cell further comprises a second cathode having a different composition than the anode and comprising Cu, Ni, Fe, or a combination thereof, the second cathode comprising a wire mesh, wherein the second cathode is arranged on an opposite side of the anode from the first cathode such that a second gap is formed between the anode and the second cathode, and wherein the conductive connector connects the second cathode to the anode and maintains the second gap.

12. The method of claim 1 , wherein the method comprises immersing a plurality of the electrochemical cells in the water comprising phosphorus.

13. The method of claim 12 , wherein the electrochemical cells are each removably attached to one or more structural connectors comprising a rod, a beam, a hangar, a bracket, a hook, or a combination thereof.

14. The method of claim 13 , wherein the electrochemical cells have one or more holes therethrough, wherein the one or more structural connectors attach to the electrochemical cells through the one or more holes in each electrochemical cell.

15. The method of claim 11 ,

wherein the anode comprises Mg and the first and second cathode comprise Cu.

16. The method of claim 11 ,

wherein the anode comprises Al and the first and second cathode comprise Cu.

17. The method of claim 11 , wherein the method comprises immersing a plurality of the electrochemical cells in the water comprising phosphorus, wherein the electrochemical cells are each attached to one or more structural connectors, and wherein the anode comprises Mg, Al, or a combination thereof, and wherein the first and second cathode comprise Cu.

18. A method of removing phosphorus from water, the method comprising:

immersing an electrochemical cell in water comprising phosphorus to form treated water comprising a salt that comprises the phosphorus, the electrochemical cell comprising

an anode comprising Mg, Al, Fe, Zn, or a combination thereof, wherein the anode comprises a planar nonporous form,

a first cathode having a different composition than the anode and comprising Cu, Ni, Fe, or a combination thereof, wherein the first cathode comprises a wire mesh, wherein the cathode is arranged parallel to a first major face of the planar nonporous form of the anode such that a first gap is formed between the major face of the planar nonporous form of the anode and the first cathode,

a second cathode having a different composition that the anode and comprising Cu, Ni, Fe, or a combination thereof, wherein the second cathode comprises a wire mesh, wherein the second cathode is arranged on an opposite side of the anode from the first cathode and parallel to a second major face of the planar nonporous form of the anode such that a second gap is formed between the second major face of the planar nonporous form of the anode and the second cathode, and

at least one conductive connector connecting the first and second cathode to the anode, wherein the conductive connector maintains the first and second gap between the first and second cathode and the anode; and

separating the salt comprising the phosphorus from the treated water, to form separated water having a lower phosphorus concentration than the water comprising phosphorus.

19. The method of claim 18 , wherein the anode comprises Al and the cathode comprises Cu.

Assignments (2)

Continuity (4)

References Cited (339)