IP Library › Granted Patent US 12,535,748
Granted Patent B2
US 12,535,748 · App. 18/046,597 · Granted Jan 27, 2026

Magnetic toner

Inventors: Hiroki Kagawa (Shizuoka, JP); Kenta Kamikura (Kanagawa, JP); Kosuke Fukudome (Tokyo, JP); Atsuhiko Ohmori (Kanagawa, JP)
Assignee: CANON KABUSHIKI KAISHA
G03G9/0836G03G9/0831G03G9/08711
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Quick Facts
Patent No.
US 12,535,748
App. No.
18/046,597
Granted
Jan 27, 2026
Kind
B2
Abstract

A magnetic toner comprising a toner particle comprising a binder resin and a magnetic body, wherein the binder resin comprises a styrene-acrylic resin, the styrene-acrylic resin comprises a monomer unit represented by Formula (1): where, in Formula (1), R 1 represents a hydrogen atom or a methyl group; and R 2 represents a linear alkyl group having C B carbon atoms, C B being an integer from 10 to 15; the magnetic body comprises an alkyl group having C M carbon atoms, on a surface of the magnetic body, C M being an integer from 4 to 20; C B and C M satisfy Formula (3): | C M −C B |≤10  (3), and in a cross-sectional observation of the magnetic toner using a transmission electron microscope, a coefficient of variation of an occupied area ratio of the magnetic body in a specific square grid, is 80.0% or lower.

Claims (20)

1 . A magnetic toner, comprising:

a toner particle comprising a binder resin, a magnetic body and an external additive;

the binder resin comprising a styrene-acrylic resin, the styrene-acrylic resin comprising monomer units represented by Formulae (1) and (5), and a monomer unit corresponding to n-butyl acrylate

where R 1 represents a hydrogen atom or a methyl group, R 2 represents a linear alkyl group having C B carbon atoms, C B is an integer of 10 to 15, and R 61 represents a hydrogen atom or a methyl group;

a content ratio of the monomer unit represented by Formula (1) in the styrene-acrylic resin being 1.0 to 10.0 mass %;

the external additive comprising a silicone oil-treated silica; and

the magnetic body being surface-treated with a compound having an alkyl group having C M carbon atoms, where C M is an integer from 4 to 20, wherein

an average circularity of the magnetic toner is 0.940 to 0.995,

| C M −C B |≤8, and

in a cross-sectional observation of the magnetic toner using a transmission electron microscope, a coefficient of variation of an occupied area ratio of the magnetic body in a square grid, resulting from demarcating a cross section of the magnetic toner in a grid of 0.8 μm-side squares, is 60.0% or lower.

2 . The magnetic toner according to claim 1 , wherein C B is 12.

3 . The magnetic toner according to claim 1 , wherein the toner particle comprises an ester compound, the ester compound being at least one member selected from the group consisting of ester compounds represented by Formulae (6)-(8)

where R 31 and R 41 represent independently an alkylene group having 2 to 8 carbon atoms, and R 32 , R 33 , R 42 , R 43 , R 51 and R 52 represent independently a linear alkyl group having 14 to 24 carbon atoms.

4 . The magnetic toner according to claim 1 , which has a thermal conductivity of 0.190 W/mK or higher measured in accordance with a hot-disk method.

5 . The magnetic toner according to claim 1 , wherein primary particles of the magnetic body have a number-average particle diameter of 50 to 500 nm, and

a standard deviation of the number-average particle diameter of the primary particles of the magnetic body is 50 to 90 nm.

6 . The magnetic toner according to claim 3 , wherein an absolute value of SPb−SPw is 2.50 or less,

when SPb (J/cm 3 ) 1/2 is a SP value of the styrene-acrylic resin and SPw (J/cm 3 ) 1/2 is a SP value of the ester compound.

7 . The magnetic toner according to claim 3 , wherein an absolute value of SPm−SPw is 1.10 or less,

when SPm (J/cm 3 ) 1/2 is a SP value of the compound having an alkyl group having C M carbon atoms and SPw (J/cm 3 ) 1/2 is a SP value of the ester compound.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 1, 2022
From: KAGAWA, HIROKI; KAMIKURA, KENTA; FUKUDOME, KOSUKE; OHMORI, ATSUHIKO
To: CANON KABUSHIKI KAISHA
Reel/Frame 061621/0977 →
Priority Claims (1)
JP 2021-171623 · Oct 20, 2021 · national
Continuity (1)
Related Publication 20230122974A1 · Apr 20, 2023
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