IP Library Granted Patent US 12,738,306
Granted Patent B2
US 12,738,306 · App. 18/600,384 · Granted Sep 15, 2026

Magnetic tunnel junction with dual reference layers having parallel magnetization directions and methods for operating the same

Inventors: Goran Mihajlovic (San Jose, CA); Wonjoon Jung (San Jose, CA)
Assignee: Sandisk Technologies, Inc.
G11C11/161G11C11/1673G11C11/1675H10B61/00H10N50/10H10N50/85
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Quick Facts
Patent No.
US 12,738,306
App. No.
18/600,384
Granted
Sep 15, 2026
Kind
B2
Abstract

A magnetoresistive memory cell includes a first electrode; a second electrode; and a layer stack located between the first electrode and the second electrode and comprising, from one end to another, a first reference layer, a first tunnel barrier layer, a free layer, a second tunnel barrier layer, and a second reference layer. A first one of the first reference layer and the second reference layer comprises a positive spin polarization material. A second one of the first reference layer and the second reference layer comprises a negative spin polarization material. A magnetization direction of the second reference layer is parallel to a magnetization direction of the first reference layer.

Claims (52)

1 . A device comprising a magnetoresistive memory cell which comprises:

a first electrode;

a second electrode; and

a layer stack located between the first electrode and the second electrode and comprising, from one end to another, a first reference layer, a first tunnel barrier layer, a free layer, a second tunnel barrier layer, and a second reference layer,

wherein:

a first one of the first reference layer and the second reference layer comprises a positive spin polarization material, wherein the positive spin polarization material causes a spin direction of electrons passing through the positive spin polarization material to align along a magnetization direction of the positive spin polarization material;

a second one of the first reference layer and the second reference layer comprises a negative spin polarization material, wherein the negative spin polarization material causes a spin direction of electrons passing through the negative spin polarization material to align along an opposite direction of a magnetization direction of the negative spin polarization material; and

a magnetization direction of the second reference layer is parallel to a magnetization direction of the first reference layer.

2 . The device of claim 1 , wherein the device comprises a spin transfer torque (STT) magnetoresistive random memory (MRAM) array comprising a plurality of dual magnetic tunnel junction STT-MRAM memory cells.

3 . The device of claim 1 , wherein the magnetoresistive memory cell further comprises a first magnetic polarizer layer located between the first electrode and the first reference layer.

4 . The device of claim 3 , further comprising a first antiferromagnetic coupling layer is located between the first magnetic polarizer layer and the first reference layer.

5 . The device of claim 4 , wherein the first magnetic polarizer layer has a magnetization direction that is antiparallel to the magnetization direction of the first reference layer.

6 . The device of claim 4 , wherein the first magnetic polarizer layer comprises a hard magnetization layer or a ferromagnetic multilayer structure including a superlattice, an exchange-bias-inducing antiferromagnetic layer, or a stack of at least one ferromagnetic material layer and at least one antiferromagnetic layer.

7 . The device of claim 4 , wherein the magnetoresistive memory cell further comprises a second magnetic polarizer layer located between the second electrode and the second reference layer.

8 . The device of claim 7 , further comprising a second antiferromagnetic coupling layer is located between the second magnetic polarizer layer and the second reference layer.

9 . The device of claim 7 , wherein:

the second magnetic polarizer layer has a magnetization direction that is antiparallel to the magnetization direction of the second reference layer; and

the magnetization direction of the first magnetic polarizer layer is parallel to the magnetization direction of the second magnetic polarizer layer.

10 . The device of claim 1 , wherein:

the first tunnel barrier layer is in contact with a first surface of the free layer and with a surface of the first reference layer; and

the second tunnel barrier layer is in contact with a second surface of the free layer and with a surface of the second reference layer.

11 . The device of claim 1 , wherein:

the second reference layer overlies the first reference layer;

the first reference layer comprises the positive spin polarization material; and

the second reference layer comprises the negative spin polarization material.

12 . The device of claim 1 , wherein:

the second reference layer overlies the first reference layer;

the first reference layer comprises the negative spin polarization material; and

the second reference layer comprises the positive spin polarization material.

13 . The device of claim 1 , wherein:

the positive spin polarization material comprises Fe, Co, Ni or an alloy thereof; and

the negative spin polarization material comprises Fe 1-x Cr x where x<0.7, a Mn 2 VGa Heusler alloy, Fe 4 N or SrRuO 3 .

14 . The device of claim 1 , wherein:

the layer stack is a vertical stack in which the first reference layer, the first tunnel barrier layer, the free layer, the second tunnel barrier layer, the second reference layer are arranged along a vertical direction; and

the layer stack is located over a support.

15 . A method of operating a spin transfer torque (STT) magnetoresistive random memory (MRAM) device, comprising:

providing a magnetoresistive memory cell which comprises a first electrode, a second electrode, and a layer stack located between the first electrode and the second electrode and comprising, from one end to another, a first reference layer, a first tunnel barrier layer, a free layer, a second tunnel barrier layer, a second reference layer, wherein the first reference layer and the second reference layer have magnetization directions that are parallel to each other, and wherein a first one of the first reference layer and the second reference layer comprises a positive spin polarization material, wherein the positive spin polarization material causes a spin direction of electrons passing through the positive spin polarization material to align along a magnetization direction of the positive spin polarization material, and a second one of the first reference layer and the second reference layer comprises a negative spin polarization material, wherein the negative spin polarization material causes a spin direction of electrons passing through the negative spin polarization material to align along an opposite direction of a magnetization direction of the negative spin polarization material;

applying a read bias across the first electrode and the second electrode while the magnetization directions of the first reference layer and the second reference layer are parallel to each other; and

determining a magnetization direction of the free layer relative to the magnetization directions of the first reference layer and the second reference layer based on a magnitude of electrical current that flows through the layer stack under the read bias.

16 . The method of claim 15 , further comprising programming the magnetoresistive memory cell into a parallel state in which the magnetization direction of the free layer is parallel to the magnetization directions of the first reference layer and the second reference layer by flowing a programming electrical current through the free layer while the magnetization directions of the first reference layer and the second reference layer are parallel to each other.

17 . The method of claim 15 , further comprising programming the magnetoresistive memory cell into an antiparallel state in which the magnetization direction of the free layer is antiparallel to the magnetization directions of the first reference layer and the second reference layer by flowing a programming electrical current through the free layer while the magnetization directions of the first reference layer and the second reference layer are parallel to each other, wherein the magnetoresistive memory cell stores binary data only in the parallel state and the antiparallel state.

18 . The method of claim 15 , wherein:

the positive spin polarization material comprises Fe, Co, Ni or an alloy thereof; and

the negative spin polarization material comprises Fe 1-x Cr x where x<0.7, a Mn 2 VGa Heusler alloy, Fe 4 N or SrRuO 3 .

19 . The method of claim 15 , wherein the magnetoresistive memory cell further comprises:

a first magnetic polarizer layer located between the first electrode and the first reference layer;

a first antiferromagnetic coupling layer is located between the first magnetic polarizer layer and the first reference layer;

a second magnetic polarizer layer located between the second electrode and the second reference layer; and

a second antiferromagnetic coupling layer is located between the second magnetic polarizer layer and the second reference layer.

20 . The device of claim 1 , wherein the magnetoresistive memory cell is configured to store binary data by being in one of only two stable data states consisting of:

a parallel state in which the magnetization direction of the free layer is parallel to the magnetization directions of the first and second reference layers; and

an antiparallel state in which the magnetization direction of the free layer is antiparallel to the magnetization directions of the first and second reference layers.

Assignments (4)
PARTIAL RELEASE OF SECURITY INTERESTS Recorded Apr 25, 2025
From: JPMORGAN CHASE BANK, N.A., AS AGENT
To: SANDISK TECHNOLOGIES, INC.
Reel/Frame 071382/0001 →
SECURITY AGREEMENT Recorded Apr 25, 2025
From: SANDISK TECHNOLOGIES, INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 071050/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 31, 2024
From: SANDISK TECHNOLOGIES LLC
To: SANDISK TECHNOLOGIES, INC.
Reel/Frame 069796/0423 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 19, 2024
From: MIHAJLOVIC, GORAN; JUNG, WONJOON
To: SANDISK TECHNOLOGIES LLC
Reel/Frame 066829/0451 →
Continuity (1)
Related Publication 20250285669A1 · Sep 11, 2025
References Cited (76)
US 6667901B1 · Perner et al. · 2003 [cited by applicant]
US 6744086B2 · Daughton · 2004 [cited by examiner]
US 6795280B1 · Song et al. · 2004 [cited by applicant]
US 8058696B2 · Ranjan et al. · 2011 [cited by applicant]
US 8344242B2 · Fiorenza et al. · 2013 [cited by applicant]
US 8374048B2 · Apalkov · 2013 [cited by applicant]
US 8399941B2 · Apalkov et al. · 2013 [cited by applicant]
US 8422285B2 · Apalkov et al. · 2013 [cited by applicant]
US 8766383B2 · Apalkov et al. · 2014 [cited by applicant]
US 9184375B1 · Tang et al. · 2015 [cited by applicant]
US 9508890B2 · Li et al. · 2016 [cited by applicant]
US 9508924B2 · Tang et al. · 2016 [cited by applicant]
US 9595917B2 · Kan et al. · 2017 [cited by applicant]
US 9792971B2 · Carey et al. · 2017 [cited by applicant]
US 9805444B2 · Lee et al. · 2017 [cited by applicant]
US 9818931B2 · Tang et al. · 2017 [cited by applicant]
US 10276226B2 · Schafer et al. · 2019 [cited by applicant]
US 10333058B2 · Aradhya · 2019 [cited by examiner]
US 10522746B1 · Sundar et al. · 2019 [cited by applicant]
US 10622547B2 · Chia · 2020 [cited by examiner]
US 10719298B1 · Braganca · 2020 [cited by applicant]
US 10964748B1 · Prasad · 2021 [cited by examiner]
US 10991407B1 · Prasad et al. · 2021 [cited by applicant]
US 11005034B1 · Prasad et al. · 2021 [cited by applicant]
US 11056640B2 · Prasad et al. · 2021 [cited by applicant]
US 11127422B1 · Liu et al. · 2021 [cited by applicant]
US 11217626B2 · Campiglio et al. · 2022 [cited by applicant]
US 11283006B1 · Freitag et al. · 2022 [cited by applicant]
US 11361805B2 · Mihajlovic et al. · 2022 [cited by applicant]
US 11404632B2 · Prasad · 2022 [cited by applicant]
US 11587708B2 · Nguyen et al. · 2023 [cited by applicant]
US 11793002B2 · Woo · 2023 [cited by examiner]
US 12336189B2 · Sasaki · 2025 [cited by examiner]
US 20060083057A1 · Nakayama et al. · 2006 [cited by applicant]
US 20090273972A1 · Han et al. · 2009 [cited by applicant]
US 20090303779A1 · Chen et al. · 2009 [cited by applicant]
US 20100020592A1 · Hosotani et al. · 2010 [cited by applicant]
US 20100053822A1 · Xi et al. · 2010 [cited by applicant]
US 20100078742A1 · Zheng et al. · 2010 [cited by applicant]
US 20100080054A1 · Abe · 2010 [cited by applicant]
US 20110133299A1 · Zhu et al. · 2011 [cited by applicant]
US 20120015099A1 · Sun et al. · 2012 [cited by applicant]
US 20120250391A1 · Cambou · 2012 [cited by applicant]
US 20120290773A1 · Naccache · 2012 [cited by applicant]
US 20150294707A1 · Apalkov et al. · 2015 [cited by applicant]
US 20160171135A1 · Datta et al. · 2016 [cited by applicant]
US 20170263856A1 · Iwayama · 2017 [cited by applicant]
US 20180061467A1 · Kan et al. · 2018 [cited by applicant]
US 20190206464A1 · Tzoufras et al. · 2019 [cited by applicant]
US 20200341079A1 · Swerts et al. · 2020 [cited by applicant]
US 20200365195A1 · Couet et al. · 2020 [cited by applicant]
US 20210126190A1 · Couet et al. · 2021 [cited by applicant]
US 20210135090A1 · Sun · 2021 [cited by applicant]
US 20210135091A1 · Park et al. · 2021 [cited by applicant]
US 20210210677A1 · Prasad · 2021 [cited by applicant]
US 20210320245A1 · Kalitsov et al. · 2021 [cited by applicant]
US 20210336128A1 · Reznicek et al. · 2021 [cited by applicant]
US 20220013714A1 · Park et al. · 2022 [cited by applicant]
US 20220093305A1 · Diao et al. · 2022 [cited by applicant]
US 20220301612A1 · Worledge et al. · 2022 [cited by applicant]
US 20220302368A1 · Worledge et al. · 2022 [cited by applicant]
US 20230084970A1 · Okamura et al. · 2023 [cited by applicant]
US 20230119656A1 · Hong et al. · 2023 [cited by applicant]
US 20240005973A1 · Le et al. · 2024 [cited by applicant]
US 20240006109A1 · Le et al. · 2024 [cited by applicant]
US 20240032437A1 · Le et al. · 2024 [cited by applicant]
US 20250384909A1 · Wan · 2025 [cited by examiner]
US 20250384926A1 · Mihajlovic · 2025 [cited by examiner]
Hu, G. et al., “STT-MRAM with double magnetic tunnel junctions,” IEDM 2015, 668 (2015). [cited by applicant]
Sunaga, K et al., “Inverse tunnel magnetoresistance in magnetic tunnel junctions with an Fe4N electrode,” Journal of Applied Physics 102, 013917, 2007. [cited by applicant]
Suto, H et al., “Negative spin polarization of Mn2VGa Heusler alloy thin film studied in current-perpendicular-to-plane giant magnetoresistance devices,” 2023 IEEE International Magnetic Conference, Short papers, 10.110… [cited by applicant]
Suto, H et al., “Study on FeCr thin film for a spintronic material with negative spin polarization,” Journal of Magnetism and Magnetic Materials 557 (2022) 169474. [cited by applicant]
Worledge, D.C., et al., “STT-MRAM—Status and outlook”, Session D1 TMRC 2022, The 33rd Magnetic Recording Conference Digests, Hosted by Western Digital, Milpitas, CA, pp. 52-53 (Aug. 2022). DOI: 10.1109/TMRC56419.2022.99… [cited by applicant]
Worledge, D.C., “Theory of Spin Torque Switching Current for the Double Magnetic Tunnel Junction,” IEEE Magnetics Letters, vol. 8 (2017) DOI: 10.1109/LMAG.2017.27073. [cited by applicant]
Yasui, S. et al., “Large Inverse Tunnel Magnetoresistance in Magnetic Tunnel Junctions with an Fe3O4 Electrode,” Physical Review Applied 15, 034042 (2021); DOI: 10.1103/PhysRevApplied.15.034042. [cited by applicant]
U.S. Appl. No. 18/065,098, filed Dec. 13, 2022, Western Digital Technologies, Inc. [cited by applicant]