IP Library › Granted Patent US 12,334,238
Granted Patent B2
US 12,334,238 · App. 18/519,085 · Granted Jun 17, 2025

MRAM stacks, MRAM devices and methods of forming the same

Inventors: Shy-Jay Lin (Hsinchu County, TW); Wilman Tsai (Saratoga, CA); Ming-Yuan Song (Hsinchu, TW)
Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
H01F10/329G11C11/161H01F10/3259H01F10/3286H01F41/32H10B61/22H10N50/01H10N50/80H10N50/85
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Quick Facts
Patent No.
US 12,334,238
App. No.
18/519,085
Granted
Jun 17, 2025
Kind
B2
Abstract

Memory stacks, memory devices and method of forming the same are provided. A memory stack includes a spin-orbit torque layer, a magnetic bias layer and a free layer. The magnetic bias layer is in physical contact with the spin-orbit torque layer and has a first magnetic anisotropy. The free layer is disposed adjacent to the spin-orbit torque layer and has a second magnetic anisotropy perpendicular to the first magnetic anisotropy.

Claims (45)

1. A memory stack, comprising:

a heavy metal layer;

a synthetic free layer disposed over the heavy metal layer and comprising:

a first free layer with a first magnetic anisotropy perpendicular to a upper surface of the heavy metal layer;

a second free layer with a second magnetic anisotropy parallel to the upper surface of the heavy metal layer; and

a non-magnetic metal spacer disposed between and in direct contact with the first free layer and the second free layer;

a reference layer disposed over the synthetic free layer; and

a synthetic anti-ferromagnetic layer disposed over the reference layer and configured to fix a magnetic anisotropy of the reference layer.

2. The memory stack of claim 1 , wherein the first free layer is in direct contact with the heavy metal layer.

3. The memory stack of claim 1 , wherein the first free layer comprises Co, CoNi or a combination thereof.

4. The memory stack of claim 1 , wherein the second free layer comprises Fe, Co, Ni, FeCo, CoNi, CoFeB, FeB, FePt, FePd or a combination thereof.

5. The memory stack of claim 1 , wherein the non-magnetic metal spacer comprises PtCo, WCoFeB, Ru, RuFe, RuCo, Ir, IrFe, IrCo or a combination thereof.

6. The memory stack of claim 1 , further comprising:

a tunneling barrier layer disposed between the reference layer and the synthetic free layer.

7. A memory device, comprising:

a substrate; and

a MRAM cell disposed over the substrate and comprising:

a bottom electrode;

a heavy metal layer disposed over the bottom electrode;

a synthetic free layer disposed over the heavy metal layer and comprising two layers configured to have magnetic anisotropies perpendicular to each other;

a reference layer disposed over the synthetic free layer; and

a synthetic anti-ferromagnetic layer disposed over the reference layer and configured to fix a magnetic anisotropy of the reference layer;

a top electrode disposed over the synthetic anti-ferromagnetic layer, wherein a sidewall of the top electrode is flush with a sidewall of the synthetic free layer.

8. The memory device of claim 7 , wherein the layer of the synthetic free layer that is in physical contact with the heavy metal layer forms a perpendicular magnetic anisotropy with the heavy metal layer.

9. The memory device of claim 7 , further comprising:

a tunneling barrier layer disposed between the reference layer and the synthetic free layer.

10. A memory stack, comprising:

a metal layer;

a synthetic free layer disposed over the metal layer and comprising:

a first free layer with a first magnetic anisotropy perpendicular to a upper surface of the metal layer; and

a second free layer with a second magnetic anisotropy parallel to the upper surface of the metal layer;

a reference layer disposed over the synthetic free layer; and

a synthetic anti-ferromagnetic layer, disposed over the reference layer and configured to fix a magnetic anisotropy of the reference layer,

wherein a width of the metal layer is different from a width of the synthetic free layer.

11. The memory stack of claim 10 , wherein the width of the metal layer is greater than the width of the synthetic free layer.

12. The memory stack of claim 10 , wherein the first free layer is in direct contact with the metal layer.

13. The memory stack of claim 10 , wherein the first free layer and the second free layer are separated from each other.

14. The memory stack of claim 10 , wherein the synthetic anti-ferromagnetic layer comprises at least one non-magnetic metal layer and at least one pinned ferromagnetic layer adjacent to each other.

15. The memory stack of claim 10 , further comprising:

a tunneling barrier layer disposed between the reference layer and the synthetic free layer.

16. The memory stack of claim 10 , wherein the metal layer comprises W, Pt, AuPt or a combination thereof.

17. The memory stack of claim 10 , wherein the first free layer comprises Co, CoNi or a combination thereof.

18. The memory stack of claim 10 , wherein the second free layer comprises FeCo, CoFeB, FeB or a combination thereof.

19. The memory stack of claim 10 , further comprising a capping structure disposed over the synthetic anti-ferromagnetic layer.

20. The memory stack of claim 19 , wherein the capping structure comprises a first capping layer and an overlaying second capping layer, and the first capping layer and the second capping layer comprise different metal materials.

Continuity (4)
Continuation 17876587 · Jul 29, 2022
Continuation 16805863 · Mar 2, 2020
Provisional Application 62849163 · May 17, 2019
Related Publication 20240087786A1 · Mar 14, 2024
References Cited (30)
US 9608039B1 · Apalkov · 2017 [cited by examiner]
US 10127956B2 · Lee · 2018 [cited by examiner]
US 10170694B1 · Shirotori · 2019 [cited by examiner]
US 10302711B2 · Wang · 2019 [cited by examiner]
US 10586579B2 · Wang · 2020 [cited by examiner]
US 10636840B2 · Manipatruni · 2020 [cited by examiner]
US 10964468B2 · Salahuddin · 2021 [cited by examiner]
US 20150311901A1 · Bromberg · 2015 [cited by examiner]
US 20170316813A1 · Lee · 2017 [cited by examiner]
US 20180151210A1 · Li · 2018 [cited by examiner]
US 20180203077A1 · Wang · 2018 [cited by examiner]
US 20190103552A1 · Shiokawa · 2019 [cited by examiner]
US 20190131519A1 · Ikegawa · 2019 [cited by examiner]
US 20190228894A1 · Hara · 2019 [cited by examiner]
US 20190295617A1 · Wang · 2019 [cited by examiner]
US 20190304523A1 · O'Brien · 2019 [cited by examiner]
US 20190304524A1 · Oguz · 2019 [cited by examiner]
US 20190304653A1 · Oguz · 2019 [cited by examiner]
US 20190312086A1 · Manipatruni · 2019 [cited by examiner]
US 20190326353A1 · O'Brien · 2019 [cited by examiner]
US 20190386205A1 · Gosavi · 2019 [cited by examiner]
US 20200006424A1 · Sato · 2020 [cited by examiner]
US 20200006630A1 · Sato · 2020 [cited by examiner]
US 20200006631A1 · Sato · 2020 [cited by examiner]
US 20200013444A1 · Min · 2020 [cited by examiner]
US 20200105998A1 · Smith · 2020 [cited by examiner]
US 20200227104A1 · Rahman · 2020 [cited by examiner]
US 20200227105A1 · Gosavi · 2020 [cited by examiner]
US 20200227474A1 · O'Brien · 2020 [cited by examiner]
US 20200343301A1 · Buford · 2020 [cited by examiner]