IP Library Granted Patent US 12,362,352
Granted Patent B2
US 12,362,352 · App. 18/149,494 · Granted Jul 15, 2025

Negative electrodes for electrochemical cells

Inventors: Rupak Chakraborty (Brookline, MA); Jarrod David Milshtein (Arlington, MA); Eric Weber (Pittsburgh, PA); William Henry Woodford (Cambridge, MA); Yet-Ming Chiang (Weston, MA); Ian Salmon McKay (Seattle, WA); Liang Su (Medfield, MA); Jay Whitacre (Pittsburgh, PA); Theodore Alan Wiley (Somerville, MA); Kristen Carlisle (Medford, MA); Mitchell Terrance Westwood (Boston, MA); Rachel Elizabeth Mumma (Somerville, MA); Max Rae Chu (Brookline, MA); Amelie Nina Kharey (Cambridge, MA); Benjamin Thomas Hultman (Somerville, MA); Marco Ferrara (Boston, MA); Mateo Cristian Jaramillo (San Francisco, CA); Isabella Caruso (Boston, MA); Jocelyn Newhouse (Somerville, MA)
Assignee: FORM ENERGY, INC.
H01M4/38H01M10/48H01M2004/021H01M2004/025H01M4/364H01M4/5815H01M4/624H01M12/065H01M12/08Y02E60/10
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Quick Facts
Patent No.
US 12,362,352
App. No.
18/149,494
Granted
Jul 15, 2025
Kind
B2
Abstract

Various embodiments provide a battery, a bulk energy storage system including the battery, and/or a method of operating the bulk energy storage system including the battery. In various embodiment, the battery may include a first electrode, an electrolyte, and a second electrode, wherein one or both of the first electrode and the second electrode comprises direct reduced iron (“DRI”). In various embodiments, the DRI may be in the form of pellets. In various embodiments, the pellets may comprise at least about 60 wt % iron by elemental mass, based on the total mass of the pellets. In various embodiments, one or both of the first electrode and the second electrode comprises from about 60% to about 90% iron and from about 1% to about 40% of a component comprising one or more of the materials selected from the group of SiO 2 , Al 2 O 3 , MgO, CaO, and TiO 2 .

Claims (17)

1. A battery, comprising:

a first electrode;

an electrolyte; and

a second electrode,

wherein the second electrode is a porous iron electrode comprising pellets of direct reduced iron (“DRI”), and the pellets of DRI comprise from 1 wt % to 5 wt % silica containing compounds by elemental mass, based on the total mass of the pellets of DRI.

2. The battery of claim 1 , wherein the pellets of DRI comprise at least one of iron ore, direct reduced grade iron ore, reduced taconite, wustite, magnetite, hematite, cementite, or iron oxide.

3. The battery of claim 1 , wherein the electrolyte is infiltrated into the pellets of DRI of the porous iron electrode.

4. The battery of claim 1 , further comprising a current collector electrically connected to the pellets of DRI of the porous iron electrode.

5. The battery of claim 1 , wherein the porous iron electrode is under compressive force.

6. The battery of claim 5 , wherein the compressive force on the porous iron electrode is greater than about 7 kPa and less than about 700 kPa.

7. The battery of claim 4 , wherein the pellets of DRI of the porous iron electrode are in contact with the current collector.

8. The battery of claim 1 , wherein the pellets of DRI have an average particle size greater than 10 nm and less than 1 mm.

9. The battery of claim 1 , wherein macropores are defined between the pellets of DRI, and the pellets of DRI have microporous surfaces.

10. The battery of claim 1 , wherein the pellets of DRI comprise at least about 90 wt % and less than about 98 wt % of metallic iron based on total mass of the pellets of DRI.

11. The battery of claim 1 , wherein the electrolyte comprises an alkaline liquid.

12. The battery of claim 11 , wherein the electrolyte includes an alkaline liquid, and the silica containing compounds are dissolvable in the alkaline liquid to form a gel electrolyte.

13. The battery of claim 1 , wherein the second electrode further comprises additive pellets comprising a metal sulfide.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 18, 2023
From: CHAKRABORTY, RUPAK; MILSHTEIN, JARROD DAVID; WEBER, ERIC; WOODFORD, WILLIAM HENRY; CHIANG, YET-MING; MCKAY, IAN SALMON; SU, LIANG; WHITACRE, JAY; WILEY, THEODORE ALAN; CARLISLE, KRISTEN; WESTWOOD, MITCHELL TERRANCE; MUMMA, RACHEL ELIZABETH; CHU, MAX RAE; KHAREY, AMELIE NINA; HULTMAN, BENJAMIN THOMAS; FERRARA, MARCO; JARAMILLO, MATEO CRISTIAN; CARUSO, ISABELLA; NEWHOUSE, JOCELYN
To: FORM ENERGY, INC.,
Reel/Frame 065901/0287 →
Continuity (5)
Continuation 16523722 · Jul 26, 2019
Provisional Application 62868511 · Jun 28, 2019
Provisional Application 62790668 · Jan 10, 2019
Provisional Application 62711253 · Jul 27, 2018
Related Publication 20230369576A1 · Nov 16, 2023
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