Antiomony and layered carbon network battery anode
A method is provided for fabricating an antimony anode. The method disperses antimony (Sb) particles in a layered carbon network using a process such as mechanical mixing, ball milling, stirring, or ultrasound sonication, forming a Sb/carbon composite. The Sb/carbon composite is mixed with a binder, forming a mixture, and the mixture is deposited on a current collector. Advantageously, the binder may be an aqueous (water soluble) binder. In one aspect, prior to dispersing the Sb particles in the layered carbon network, the Sb particles are coated with carbon. For example, the Sb particles may be dispersed in a solution including a polymer, where the solution may be an aqueous or organic. Alternatively, the Sb particles may be dispersed in a solution including a monomer. The monomer solution is polymerized to form polymer sheathed Sb core-shell structures, and then carbonized. Associated Sb anodes and Sb anode batteries are also provided.
1. An anode in a sodium-ion electrochemical battery, the anode comprising:
a current collector;
a layered carbon network overlying the current collector, where the layered carbon network is a material selected from a group consisting of graphite flakes or reconstituted graphene stacks;
antimony (Sb) particles embedded in the layered carbon network; and,
a conformal coating of carbon overlying the Sb particles, forming core-shell structures.
2. The anode of claim 1 wherein the Sb particles have a size in a range of 1 nanometer (nm) to 1 millimeter (mm).
3. The anode of claim 1 wherein the Sb-to-layered carbon network mass ratio is in a range of 1:100 to 100:1.
4. The anode of claim 1 further comprising:
an aqueous binder.
5. A sodium-ion electrochemical battery with an antimony anode, the battery comprising:
an anode comprising:
a current collector;
a layered carbon network overlying the current collector; where the layered carbon network is a material selected from a group consisting of graphite flakes or reconstituted graphene stacks;
antimony (Sb) particles embedded in the layered carbon network;
a cathode; and,
a non-aqueous electrolyte containing a sodium salt.
6. The battery of claim 5 wherein the layered carbon network is a material selected from a group consisting of graphite flakes or reconstituted graphene stacks.
7. The battery of claim 5 further comprising:
a conformal coating of carbon overlying the Sb particles.
8. The battery of claim 5 wherein the Sb particles have a size in a range of 1 nanometer (nm) to 1 millimeter (mm).
9. The battery of claim 5 wherein the Sb-to-layered carbon network mass ratio is in a range of 1:100 to 100:1.
10. The battery of claim 5 wherein the cathode includes:
a current collector; and,
an intercalation material overlying the current collector, comprising a material selected from a group consisting of NaCoO 2 , NaMnO 2 , NaNiO 2 , NaFePO 4 , MnO 2 , V 2 O 5 , MoO 3 , Prussian Blue analogues, sulfur, active organic materials, and combinations thereof.
11. The battery of claim 5 wherein the anode further comprises:
an aqueous binder.
12. A method for fabricating a sodium-ion electrochemical battery antimony anode, the method comprising:
providing antimony (Sb) particles;
coating the Sb particles with carbon, forming core-shell structures;
dispersing the core-shell structure Sb particles in a layered carbon network using a process selected from a group consisting of mechanical mixing, ball milling, stirring, or ultrasound sonication, forming a Sb/carbon composite, where the layered carbon network is a material selected from a group consisting of graphite flakes or reconstituted graphene stacks;
mixing the Sb/carbon composite with a binder, forming a mixture; and,
depositing the mixture on a current collector.
13. The method of claim 12 wherein coating the Sb particles with carbon includes:
dispersing the Sb particles in a solution including a polymer; and,
carbonizing the polymer.
14. The method of claim 13 wherein dispersing the core-shell structure Sb particles in the layered carbon network includes using a solution selected from a group consisting of aqueous and organic solvents.
15. The method of claim 12 wherein coating the Sb particles with carbon includes:
dispersing the Sb particles in a solution including a monomer;
polymerizing the monomer solution to form polymer sheathed Sb core-shell structures; and,
carbonizing the polymer shells.
16. The method of claim 12 wherein providing the Sb particles includes providing Sb particles having a size in a range of 1 nanometer (nm) to 1 millimeter (mm).
17. The method of claim 12 wherein dispersing the core-shell structure Sb particles in the layered carbon network includes the Sb particle-to-layered carbon network mass being in a ratio in a range of 1:100 to 100:1.
18. The method of claim 12 wherein mixing the Sb/carbon composite with the binder includes mixing with an aqueous binder.
19. A method for fabricating an antimony anode, the method comprising:
providing antimony (Sb) particles;
coating the Sb particles with carbon as follows:
dispersing the Sb particles in a solution including a monomer;
polymerizing the monomer solution to form polymer sheathed Sb core-shell structures;
carbonizing the polymer shells;
dispersing the Sb particles in a layered carbon network using a process selected from a group consisting of mechanical mixing, ball milling, stirring, or ultrasound sonication, forming a Sb/carbon composite; where the layered carbon network is a material selected from a group consisting of graphite flakes or reconstituted graphene stacks;
mixing the Sb/carbon composite with a binder, forming a mixture; and,
depositing the mixture on a current collector.