Methods for forming a transition metal nitride film on a substrate by atomic layer deposition and related semiconductor device structures
Methods for forming a transition metal nitride film on a substrate by atomic layer deposition and related semiconductor device structures are provided. In some embodiments, methods may include contacting a substrate with a first vapor phase reactant comprising a transition metal precursor and contacting the substrate with a second vapor phase reactant comprising an alkyl-hydrazine precursor. In some embodiments, related semiconductor device structures may include a PMOS transistor gate structure, the PMOS transistor gate structure including a transition metal nitride film and a gate dielectric between the transition nitride film and a semiconductor body. The transition metal nitride film includes a predominant (200) crystallographic orientation.
1. A method for forming a transition metal nitride film on a substrate by atomic layer deposition, the method comprising:
contacting the substrate with a first vapor phase reactant comprising a transition metal precursor; and
contacting the substrate with a second vapor phase reactant comprising an alkyl-hydrazine precursor, wherein the alkyl-hydrazine precursor comprises at least one of tertbutylhydrazine (C 4 H 9 N 2 H 3 ), methylhydrazine (CH 3 NHNH 2 ), dimethylhydrazine ((CH 3 ) 2 N 2 H 2 ).
2. The method of claim 1 , further comprising selecting the transition metal precursor to comprise one of a titanium precursor, a tantalum precursor, a tungsten precursor or a niobium precursor.
3. The method of claim 2 , further comprising selecting the titanium precursor to comprise a titanium halide.
4. The method of claim 3 , further comprising selecting the titanium halide to comprise titanium tetrachloride (TiCl 4 ).
5. The method of claim 1 , wherein the method comprises at least one deposition cycle in which the substrate is alternately and sequentially contacted with the first vapor phase reactant and the second vapor phase reactant.
6. The method of claim 5 , wherein the deposition cycle is repeated two or more times.
7. The method of claim 1 , further comprising forming the transition metal nitride film to comprise a predominant (200) crystallographic orientation.
8. The method of claim 1 , further comprising forming the transition metal nitride film to a thickness of approximately less than 50 Angstroms.
9. The method of claim 1 , further comprising forming a gate electrode structure comprising the transition metal nitride film, the gate electrode structure having an effective work function greater than 4.2 eV.
10. The method of claim 1 , further comprising forming the transition metal nitride film to have an atomic concentration of carbon greater than 0.5%.
11. The method of claim 1 , further comprising heating the substrate to a temperature of approximately greater than approximately 350° C.
12. A reaction system configured to perform the method of claim 1 .
13. A method for forming a transition metal nitride film on a substrate by atomic layer deposition, the method comprising:
contacting the substrate with a first vapor phase reactant comprising a transition metal precursor; and
contacting the substrate with a second vapor phase reactant comprising an alkyl-hydrazine precursor,
wherein the method comprises at least one deposition cycle in which the substrate is alternately and sequentially contacted with the first vapor phase reactant and the second vapor phase reactant, and
wherein the deposition cycle is repeated two or more times.
14. The method of claim 13 , further comprising selecting the transition metal precursor to comprise one of a titanium precursor, a tantalum precursor, a tungsten precursor or a niobium precursor.
15. The method of claim 13 , further comprising forming the transition metal nitride film to comprise a predominant (200) crystallographic orientation.
16. A method for forming a transition metal nitride film on a substrate by atomic layer deposition, the method comprising:
contacting the substrate with a first vapor phase reactant comprising a transition metal precursor;
contacting the substrate with a second vapor phase reactant comprising an alkyl-hydrazine precursor; and
forming the transition metal nitride film to comprise a predominant (200) crystallographic orientation.
17. The method of claim 16 , further comprising forming the transition metal nitride film to a thickness of approximately less than 50 Angstroms.
18. A method for forming a transition metal nitride film on a substrate by atomic layer deposition, the method comprising:
contacting the substrate with a first vapor phase reactant comprising a transition metal precursor;
contacting the substrate with a second vapor phase reactant comprising an alkyl-hydrazine precursor; and
forming the transition metal nitride film to have an atomic concentration of carbon greater than 0.5%.
19. The method of claim 18 , further comprising selecting the transition metal precursor to comprise one of a titanium precursor, a tantalum precursor, a tungsten precursor or a niobium precursor.
20. The method of claim 18 , wherein the method comprises at least one deposition cycle in which the substrate is alternately and sequentially contacted with the first vapor phase reactant and the second vapor phase reactant.