IP Library › Granted Patent US 12,225,828
Granted Patent B2
US 12,225,828 · App. 18/065,098 · Granted Feb 11, 2025

Voltage controlled magnetic anisotropy (VCMA) memory devices including platinum containing layer in contact with free layer

Inventors: Alan Kalitsov (San Jose, CA); Bhagwati Prasad (San Jose, CA); Rajesh Chopdekar (San Jose, CA); Lei Wan (San Jose, CA); Tiffany Santos (Palo Alto, CA)
Assignee: Sandisk Technologies, Inc.
H10N50/10G11C11/161G11C11/1697H01F10/3286H10B61/00H10N50/80H10N50/85
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Quick Facts
Patent No.
US 12,225,828
App. No.
18/065,098
Granted
Feb 11, 2025
Kind
B2
Abstract

A memory device includes a first electrode, a second electrode, and a magnetic tunnel junction located between the first electrode and the second electrode. The magnetic tunnel junction includes a reference layer, a free layer, a nonmagnetic tunnel barrier layer located between the reference layer and the free layer, and a platinum-containing layer containing platinum and at least one element selected from iridium, hafnium or ruthenium. The platinum-containing layer contacts the free layer.

Claims (44)

1. A memory device, comprising:

a first electrode;

a second electrode; and

a magnetic tunnel junction located between the first electrode and the second electrode and comprising:

a reference layer;

a free layer;

a nonmagnetic tunnel barrier layer located between the reference layer and the free layer; and

a platinum-containing layer comprising platinum and at least one element selected from iridium, hafnium or ruthenium, wherein the platinum-containing layer contacts the free layer.

2. The memory device of claim 1 , wherein the platinum-containing layer comprises an alloy of the platinum and the at least one element selected from iridium, hafnium or ruthenium.

3. The memory device of claim 1 , wherein the platinum-containing layer comprises a layer stack of a first sublayer comprising the platinum and a second sublayer comprising the at least one element selected from iridium, hafnium or ruthenium.

4. The memory device of claim 1 , wherein the platinum-containing layer comprises a first sublayer comprising platinum and having a thickness less than 1 nm intermixed with a second sublayer comprising the at least one element selected from iridium, hafnium or ruthenium and having a thickness less than 1 nm.

5. The memory device of claim 1 , wherein:

the platinum-containing layer comprises platinum atoms at an atomic fraction in a range from 0.2 to 0.8;

the platinum-containing layer comprises iridium, hafnium, or ruthenium at an atomic fraction in a range from 0.2 to 0.8; and

the platinum-containing layer has a thickness in a range from 0.1 nm to 0.4 nm.

6. The memory device of claim 1 , wherein the memory device further comprises a dielectric capping layer located between the free layer and the second electrode.

7. The memory device of claim 6 , wherein the platinum-containing layer directly contacts the nonmagnetic tunnel barrier layer, and the dielectric capping layer is spaced from the platinum-containing layer by the free layer.

8. The memory device of claim 6 , wherein the platinum-containing layer does not directly contact the nonmagnetic tunnel barrier layer, and the dielectric capping layer is in direct contact with the platinum-containing layer.

9. The memory device of claim 1 , wherein the at least one element selected from iridium, hafnium or ruthenium comprises the iridium.

10. The memory device of claim 1 , wherein the at least one element selected from iridium, hafnium or ruthenium comprises the hafnium.

11. The memory device of claim 1 , wherein the memory device comprises a voltage controlled magnetic anisotropy magnetic memory device.

12. A memory device, comprising:

a first electrode;

a second electrode; and

a magnetic tunnel junction located between the first electrode and the second electrode and comprising:

a reference layer;

a free layer;

a nonmagnetic tunnel barrier layer located between the reference layer and the free layer;

a platinum layer contacting a first surface of the free layer; and

a metal layer comprising at least one element selected from iridium or hafnium and contacting a second surface of the free layer.

13. The memory device of claim 12 , wherein the metal layer consists essentially of the iridium.

14. The memory device of claim 12 , wherein the metal layer consists essentially of the hafnium.

15. The memory device of claim 12 , wherein:

the platinum layer has a thickness in a range from 0.05 nm to 0.3 nm; and

the metal layer has a thickness in a range from 0.05 nm to 0.3 nm.

16. The memory device of claim 12 , wherein the platinum layer directly contacts the nonmagnetic tunnel barrier layer.

17. The memory device of claim 12 , wherein the metal layer directly contacts the nonmagnetic tunnel barrier layer.

18. The memory device of claim 12 , wherein:

the memory device further comprises a dielectric capping layer located between the free layer and the second electrode; and

the dielectric capping layer is in direct contact with the metal layer.

19. The memory device of claim 12 , wherein:

the memory device further comprises a dielectric capping layer located between the free layer and the second electrode; and

the dielectric capping layer is in direct contact with the platinum layer.

20. The memory device of claim 12 , wherein the memory device comprises a voltage controlled magnetic anisotropy magnetic memory device.

Assignments (8)
PARTIAL RELEASE OF SECURITY INTERESTS Recorded Apr 25, 2025
From: JPMORGAN CHASE BANK, N.A., AS AGENT
To: SANDISK TECHNOLOGIES, INC.
Reel/Frame 071382/0001 →
SECURITY AGREEMENT Recorded Apr 25, 2025
From: SANDISK TECHNOLOGIES, INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 071050/0001 →
PATENT COLLATERAL AGREEMENT Recorded Aug 23, 2024
From: SANDISK TECHNOLOGIES, INC.
To: JPMORGAN CHASE BANK, N.A., AS THE AGENT
Reel/Frame 068762/0494 →
CHANGE OF NAME Recorded Jun 27, 2024
From: SANDISK TECHNOLOGIES, INC.
To: SANDISK TECHNOLOGIES, INC.
Reel/Frame 067982/0032 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 29, 2024
From: WESTERN DIGITAL TECHNOLOGIES, INC.
To: SANDISK TECHNOLOGIES, INC.
Reel/Frame 067567/0682 →
PATENT COLLATERAL AGREEMENT - DDTL LOAN AGREEMENT Recorded Aug 21, 2023
From: WESTERN DIGITAL TECHNOLOGIES, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 067045/0156 →
PATENT COLLATERAL AGREEMENT - A&R LOAN AGREEMENT Recorded Aug 21, 2023
From: WESTERN DIGITAL TECHNOLOGIES, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 064715/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 10, 2023
From: KALITSOV, ALAN; PRASAD, BHAGWATI; CHOPDEKAR, RAJESH; WAN, LEI; SANTOS, TIFFANY
To: WESTERN DIGITAL TECHNOLOGIES, INC.,
Reel/Frame 063273/0462 →
Continuity (5)
Continuation In Part 17358990 · Jun 25, 2021
Continuation In Part 17341049 · Jun 7, 2021
Continuation In Part 17203420 · Mar 16, 2021
Continuation In Part 16692965 · Nov 22, 2019
Related Publication 20230107190A1 · Apr 6, 2023
References Cited (136)
US 8946834B2 · Wang et al. · 2015 [cited by applicant]
US 8981505B2 · Moriyama et al. · 2015 [cited by applicant]
US 9159907B2 · Tang et al. · 2015 [cited by applicant]
US 9177575B1 · Gao et al. · 2015 [cited by applicant]
US 9396742B1 · Yang et al. · 2016 [cited by applicant]
US 9825217B1 · Kim et al. · 2017 [cited by applicant]
US 10186308B1 · Guarisco et al. · 2019 [cited by applicant]
US 10354710B2 · Petti et al. · 2019 [cited by applicant]
US 10438964B2 · Makala et al. · 2019 [cited by applicant]
US 10468457B1 · Zeng · 2019 [cited by examiner]
US 10580966B1 · Van Der Stratent et al. · 2020 [cited by applicant]
US 10726892B2 · Le et al. · 2020 [cited by applicant]
US 10788547B2 · Kalitsov et al. · 2020 [cited by applicant]
US 10797227B2 · Le et al. · 2020 [cited by applicant]
US 10811596B2 · Le et al. · 2020 [cited by applicant]
US 10862022B2 · Le et al. · 2020 [cited by applicant]
US 10991407B1 · Prasad · 2021 [cited by applicant]
US 11005034B1 · Prasad et al. · 2021 [cited by applicant]
US 11029604B2 · Ohtomi · 2021 [cited by applicant]
US 11031058B2 · Santos et al. · 2021 [cited by applicant]
US 11056640B2 · Prasad et al. · 2021 [cited by applicant]
US 11152047B2 · Jung et al. · 2021 [cited by applicant]
US 11176981B1 · Prasad et al. · 2021 [cited by applicant]
US 11217289B1 · Prasad et al. · 2022 [cited by applicant]
US 11361805B2 · Mihajlovic et al. · 2022 [cited by applicant]
US 11839162B2 · Kalitsov · 2023 [cited by examiner]
US 20030218225A1 · Nagai · 2003 [cited by applicant]
US 20060174473A1 · Oh et al. · 2006 [cited by applicant]
US 20080258721A1 · Guo et al. · 2008 [cited by applicant]
US 20110049659A1 · Suzuki et al. · 2011 [cited by applicant]
US 20110233503A1 · Hwang · 2011 [cited by examiner]
US 20120218813A1 · Oh et al. · 2012 [cited by applicant]
US 20120300542A1 · Uchida et al. · 2012 [cited by applicant]
US 20130146996A1 · Yu et al. · 2013 [cited by applicant]
US 20130249028A1 · Kamata et al. · 2013 [cited by applicant]
US 20140035075A1 · Zhu et al. · 2014 [cited by applicant]
US 20140035572A1 · Karr et al. · 2014 [cited by applicant]
US 20140038314A1 · Zhou · 2014 [cited by applicant]
US 20140071732A1 · Khalili Amiri et al. · 2014 [cited by applicant]
US 20140103470A1 · Shukh · 2014 [cited by applicant]
US 20140111195A1 · Kuo et al. · 2014 [cited by applicant]
US 20140124882A1 · Khalili Amiri et al. · 2014 [cited by applicant]
US 20140131652A1 · Yu · 2014 [cited by applicant]
US 20140153138A1 · Le et al. · 2014 [cited by applicant]
US 20140168812A1 · Braganca et al. · 2014 [cited by applicant]
US 20140169083A1 · Wang et al. · 2014 [cited by applicant]
US 20140197504A1 · Moriyama et al. · 2014 [cited by applicant]
US 20140226239A1 · Mihajlovic et al. · 2014 [cited by applicant]
US 20140248719A1 · Zhou et al. · 2014 [cited by applicant]
US 20140306302A1 · Jan et al. · 2014 [cited by applicant]
US 20140355152A1 · Park et al. · 2014 [cited by applicant]
US 20150002961A1 · Keener et al. · 2015 [cited by applicant]
US 20150035095A1 · Kim et al. · 2015 [cited by applicant]
US 20150078073A1 · Liu et al. · 2015 [cited by applicant]
US 20150091110A1 · Kuo et al. · 2015 [cited by applicant]
US 20150137289A1 · Khalili Amiri · 2015 [cited by applicant]
US 20150147481A1 · Braganca et al. · 2015 [cited by applicant]
US 20150154990A1 · Jiang et al. · 2015 [cited by applicant]
US 20150228891A1 · Park et al. · 2015 [cited by applicant]
US 20150285957A1 · Scherer · 2015 [cited by applicant]
US 20150285959A1 · Samuels · 2015 [cited by applicant]
US 20160012874A1 · Stainer · 2016 [cited by applicant]
US 20160211849A1 · Shin et al. · 2016 [cited by applicant]
US 20160240780A1 · Yu · 2016 [cited by applicant]
US 20160351799A1 · Xue et al. · 2016 [cited by applicant]
US 20170025472A1 · Kim et al. · 2017 [cited by applicant]
US 20170033281A1 · Hu · 2017 [cited by applicant]
US 20170084825A1 · Tsunoda · 2017 [cited by applicant]
US 20170092303A1 · Jiang et al. · 2017 [cited by applicant]
US 20170092842A1 · Khalili Amiri et al. · 2017 [cited by applicant]
US 20170117027A1 · Braganca et al. · 2017 [cited by applicant]
US 20170133075A1 · Liu et al. · 2017 [cited by applicant]
US 20170133583A1 · Lim et al. · 2017 [cited by applicant]
US 20170200499A1 · Rakshit · 2017 [cited by examiner]
US 20170287979A1 · Manipatruni et al. · 2017 [cited by applicant]
US 20170309813A1 · Naik et al. · 2017 [cited by applicant]
US 20170338403A1 · Kim et al. · 2017 [cited by applicant]
US 20170372761A1 · Lee · 2017 [cited by applicant]
US 20170372762A1 · Lee · 2017 [cited by applicant]
US 20180006213A1 · Park et al. · 2018 [cited by applicant]
US 20180277497A1 · Matsuo · 2018 [cited by applicant]
US 20180366172A1 · Wang et al. · 2018 [cited by applicant]
US 20180374866A1 · Makala et al. · 2018 [cited by applicant]
US 20190027169A1 · Xue et al. · 2019 [cited by applicant]
US 20190027201A1 · Petti et al. · 2019 [cited by applicant]
US 20190043548A1 · Park et al. · 2019 [cited by applicant]
US 20190051340A1 · Liu et al. · 2019 [cited by applicant]
US 20190080738A1 · Choi et al. · 2019 [cited by applicant]
US 20190178954A1 · Lassalle-Balier et al. · 2019 [cited by applicant]
US 20190189908A1 · Ebrahimi et al. · 2019 [cited by applicant]
US 20190206462A1 · Tzoufras et al. · 2019 [cited by applicant]
US 20190206464A1 · Tzoufras et al. · 2019 [cited by applicant]
US 20190219643A1 · Cadugan et al. · 2019 [cited by applicant]
US 20190221575A1 · Dong et al. · 2019 [cited by applicant]
US 20190237661A1 · Iwata et al. · 2019 [cited by applicant]
US 20190244649A1 · Park et al. · 2019 [cited by applicant]
US 20190304653A1 · Oguz et al. · 2019 [cited by applicant]
US 20200066319A1 · Park et al. · 2020 [cited by applicant]
US 20200090720A1 · Park et al. · 2020 [cited by applicant]
US 20200233047A1 · Kalitsov et al. · 2020 [cited by applicant]
US 20200309813A1 · Katti · 2020 [cited by applicant]
US 20200341079A1 · Swerts et al. · 2020 [cited by applicant]
US 20200357450A9 · Park et al. · 2020 [cited by applicant]
US 20210020829A1 · Park et al. · 2021 [cited by applicant]
US 20210028148A1 · Wu et al. · 2021 [cited by applicant]
US 20210159392A1 · Prasad et al. · 2021 [cited by applicant]
US 20210225421A1 · Mihajlovic et al. · 2021 [cited by applicant]
US 20210320245A1 · Kalitsov et al. · 2021 [cited by applicant]
US 20220392505A1 · Stewart et al. · 2022 [cited by applicant]
US 20220392953A1 · Kalitsov et al. · 2022 [cited by applicant]
US 20220393100A1 · Kalitsov et al. · 2022 [cited by applicant]
CN 103794715A · 2014 [cited by applicant]
CN 105702853A · 2016 [cited by applicant]
TW 201939778A · 2019 [cited by applicant]
WO WO2014022304A1 · 2014 [cited by applicant]
WO WO2017151735A1 · 2017 [cited by applicant]
WO WO2018004648A1 · 2018 [cited by applicant]
Ahn, C. et al., “Energy-Efficient Phase-Change Memory with Graphene as a Thermal Barrier,” American Chemical Society, Nano Lett., vol. 15, pp. 6809-6814, (2015); DOI: 10.1021/acs.nanolett.5b02661. [cited by applicant]
Gonzalez-Fuentes, C. et al., “Theory of Ferromagnetic Resonance Driven By The Combined Action Of Spin-Transfer Torque And Voltage-Controlled Magnetic Anisotropy,” Phys. Rev. B 96, 174440—(2017). [cited by applicant]
Hamalainen, J. et al., “Atomic Layer Deposition of Iridium Oxide Thin Films from Ir(acac)3 and Ozone,” Chem. Mater., vol. 20, No. 9, pp. 2903-2907, (2008); DOI: 10.1021/cm7030224. [cited by applicant]
Huang, L. et al., “Graphene/Si CMOS Hybrid Hall Integrated Circuits,” Scientific Reports, vol. 4: 5548, (2014); DOI: 10.1038/srep05548. [cited by applicant]
ISR-WO, Notification of Transmittal of the International Search Report and Written Opinion of the International Search Authority for International Patent Application No. PCT/US2020/025989, mailed Aug. 24, 2020, 17 pages. [cited by applicant]
Jan, G. et al., “High Spin Torque Efficiency of Magnetic Tunnel Junctions with MgO/CoFeB/MgO Free Layer,” Applied Physics Express, vol. 5, pp. 093008-1 to 093008-3, (2012). http://dx.doi.org/10.1143/APEX.5.093008. [cited by applicant]
Kalitsov, A. et al., “Spin-transfer torque in magnetic tunnel junctions,” Phys. Rev. B. 79, 174416 (2009). [cited by applicant]
Kwon, S. et al., “Colossal electric field control of magnetic anisotropy at ferromagnetic interfaces induced by iridium overlayer,” Phys Re. B. Solid State, vol. 99, No. 6, pp. 064434, 1-7 DOI: 10.1103/PhysRevB.99.06443… [cited by applicant]
Kwon, S. et al., “Voltage-Controlled Magnetic Anisotropy in Heterostructures with Atomically Thin Heavy Metals,” Phys. Rev. Applied, vol. 12, Issue 4, pp. 044075-1-044075-6, (2019); DOI: 10.1103/PhysRevApplied.12.044075. [cited by applicant]
Lee, S.E. et al., “Highly Enhanced TMR Ratio and Δ for Double MgO-based p-MTJ Spin-Valves with Top Co2Fe6B2 Free Layer by Nanoscale-thick Iron Diffusion-barrier,” Scientific Reports, vol. 7, No. 11907, pp. 1-9, (2017) D… [cited by applicant]
Liu, E. et al., “Top-Pinned STT-MRAM Devices With High Thermal Stability Hybrid Free Layers for High-Density Memory Applications,” IEEE Transactions on Magnetics, pp. 1-5 (2018). [cited by applicant]
Nishioka, K. et al., “Novel Quad-Interface MTJ Technology and Its First Demonstration With High Thermal Stability Factor and Switching Efficiency for STT-MRAM Beyond 2X nm,” IEEE Transactions on Electron Devices, 7 page… [cited by applicant]
Nozaki, T. et al., “Highly efficient voltage control of spin and enhanced interfacial perpendicular magnetic anisotropy in iridium-doped Fe/MgO magnetic tunnel junctions,” NPG Asia Materials (2017) 9, e451; doi:10.1038/… [cited by applicant]
Popis, M. D. et al., “Study of iridium silicide monolayers using density functional theory,” J. Appl. Phys., vol. 123, pp. 074301-1-074301-9 (2018); https://doi.org/10.1063/1.5010331. [cited by applicant]
Robertson, J., “High Dielectric Constant Gate Oxides for Metal Oxide Si Transistors,” Reports on Progress in Physics, Table-2, pp. 327, 335, (2006). [cited by applicant]
Sato, H. et al., “Perpendicular-anisotropy CoFeB—MgO magnetic tunnel junctions with a MgO/CoFeB/Ta/CoFeB/MgO recording structure,” Applied Physics Letters, vol. 101, pp. 022414-1 to 022414-4, (2012); doi: 10.1063/1.4736… [cited by applicant]
Wang, J. et al., “Magnetoelectric Memory Based on Ferromagnetic/Ferroelectric Multiferroic Heterostructure,” Materials (Basel), 2021; 14 (16): 4623, Published Aug. 17, 2021. doi:10.3390/ma14164623 (Year: 2021). [cited by applicant]
Yang, P. et al., “Epitaxial Growth of Centimeter-Scale Single-Crystal MoS 2 Monolayer on Au(111),” ACS Nano., vol. 14, No. 4, pp. 5036-5045, (2020); DOI: 10.1021/acsnano.0c01478. Epub Apr. 13, 2020. PMID: 32267670. [cited by applicant]
USPTO Office Communication, Non-Final Office Action for U.S. Appl. No. 17/358,990, mailed Mar. 31, 2023, 26 pages. [cited by applicant]
Cited By (1)
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